Thermodynamic, electrical and optical studies have been carried out on a discotic liquid crystal (DLC), namely 2, 3, 6, 7, 10, 11-hexabutyloxytriphenylene (possessing columnar phase) and its copper nanoparticles (0.6 wt%) based composite. The ionic conductivity of DLCÀcopper nanocomposite has increased by about two orders of magnitude as compared to the pure system. Dielectric permittivity has also increased. The absorption spectra for pure and nanocomposites have been studied by UVÀVis spectrophotometer. The optical study suggests that surface plasmon resonance has been introduced in DLC due to the incorporation of copper nanoparticles. It has been observed that the presence of nanoparticles has decreased the optical band gap to 3.3 eV from 4.2 eV of the pure DLC. Enhanced properties are useful for onedimensional conduction and photovoltaic applications.