The objective of this work is to investigate the influences of thermal radiation, heat generation, and buoyancy force on the time-dependent boundary layer (BL) flow across a vertical permeable plate. The fluid is unsteady, incompressible, viscous, and electrically insulating. The heat transfer mechanism happens due to free convection. The nondimensional partial differential equations of continuity, momentum, energy, and concentration are discussed using appropriate transformations. The impressions of thermal radiation and buoyancy forces are exposed in the energy and momentum equation, respectively. For numerical model, a set of nonlinear dimensionless partial differential equations can be solved using an explicit finite difference approach. The stability and convergence analyses are also established to complete the formulation of the model. The thermophysical effects of entering physical parameters on the flow, thermal, and material fields are analyzed. The variations in local and average skin friction, material, and heat transfer rates are also discussed for the physical interest. The analysis of the obtained findings is shown graphically, and relevant parameters pointedly prejudice the flow field. Studio Developer FORTRAN 6.2 and Tecplot 10.0 are applied to simulate the schematic model equations and graphical presentation numerically. The intensifying values of the magnetic field are affected decreasingly in the flow field. The temperature profiles decrease within the BL to increase the value of radiation parameters. The present study is on the consequences for petroleum engineering, agriculture engineering, extraction, purification processes, nuclear power plants, gas turbines, etc. To see the rationality of the present research, we compare these results and the results available in the literature with outstanding compatibility.