A Study on the Effect of Different Ball Milling Methods on the NH3-SCR Activity of Aluminum-Laden Bayan Obo Tailings

Abstract

Rich in Fe, Ce, Mn, Si and other elements which have good catalytic activity, Bayan Obo rare-earth tailings are naturally advantaged as the carrier of denitrification catalysts. In this paper, pseudo boehmite (γ-Al2O3) was mixed with Bayan Obo tailings using different ball milling methods for modification to prepare NH3-SCR catalysts. The effect of different mixing methods on the SCR denitrification activity at a low temperature was investigated and the prepared catalysts were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), temperature programed desorption (NH3-TPD), temperature programed reduction (H2-TPR) and other means. The conversion rate of NOx at 250–350 °C was above 80% and the highest conversion rate of NOx of 90% was achieved at 300 °C. SEM and XRD revealed that the tailings modified by pseudo boehmite (γ-Al2O3) using the ordinary ball milling method have loose structure and good dispersion of active substances, and specific surface area (BET) analysis shows that the tailings have the maximum specific surface area and pore volume. However, over grinding and secondary spheronization were observed in the tailings modified by pseudo boehmite (γ-Al2O3) using high energy ball milling method, leading to the decrease of specific surface area and pore volume, poor dispersion of active substances, and ultimately low denitrification rate.

Mechanism of SO2/H2O enhanced rare earth tailings catalysts in NH3-SCR at medium and high temperature

“…Bayan Ebo has a large amount of rare earth tailings aer beneciation, which contains a rich variety of NH 3 -SCR active elements (Fe, Ce, Mn), 14 of which rare earth elements are excellent NH 3 -SCR catalyst active components. 15 In addition, there are congenial relationships such as adjacency, leaching and encapsulation of various active minerals in rare earth tailings, and the interactions that exist between these congenial minerals can also facilitate the SCR reaction process, 16,17 so rare earth tailings are naturally excellent materials that can be used to prepare NH 3 -SCR catalysts.…”