In this paper, a new memristive chaotic system is designed, analyzed, tested, and proposed. An adaptive control synchronization mechanism for both master and slave chaotic systems is also designed. The adaptive control law of this mechanism is derived based on the Lyapunov theory. A single parameter in the slave system has been assumed to be unknown. As the parameters of the master and slave are asymptotically matched, the unknown slave parameters will be identified according to the master’s parameters. The proposed system is used in a secure communication system. The achieved results prove a simple system implementation with a high security of data transmission.