A systematic evaluation of charge-discharge behaviors, performance, and rate-capability of Al-ion batteries

Abavi-Torghabeh, Naghmeh; Kalantarian, Mohammad Mahdi; Dehkhoda, Sahar; Sadeghian, Zahra

doi:10.1016/j.electacta.2022.141508

Cited by 17 publications

(8 citation statements)

References 41 publications

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“…The results only show the effect of active particles. Also, estimating the goodness of the active particles (ignoring the preparation and assembly parameters [ 10 ] ) helps to evaluate the synthesis route. By the normalization, the effect of the electrode formula ( C th ) is ignored [8c] …”

Section: Resultsmentioning

confidence: 99%

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Evaluation of MXene Ti₃C₂ Charge–Discharge Behaviors as an Electrode Material for Intercalation Batteries

Khalaj,

Shahpouri,

Khakpour

et al. 2024

Energy Tech

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Eliminating A element from the MAX phases, the resulted 2D structure, named MXene, can be used as the electrode material for the intercalation, namely, Li‐ion, Na‐ion, K‐ion, and Mg‐ion batteries. MXene Ti3C2, produced by etching Ti3AlC2, is a promising intercalation electrode material, which is systematically evaluated in this article by taking data from literature. The diagrams provide a manner to assess and compare the most important characterizations, i.e., rate‐capability and performance. The evaluations show that the synthesis methods of the pristine MAX phase as well as the final MXene play vital roles on the properties. The rank of synthesis methods and also commercial pristine material is recognized and reported based on the analyzed properties. Moreover, effectiveness of the additives, dopants, compositing, nanosizing, and etching is assessed precisely. Also, comparison between different types of intercalation batteries regarding the usage of MXene as the electrode is performed. This article paves the way for future studies and evaluations of this kind of electrode materials. It guides the researchers to modify, design, and engineer their manufactured electrodes to meet higher quality of the properties.

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Section: Resultsmentioning

confidence: 99%

“…Utilizing the approaches, the best synthesis method, preparation parameters, and additives can be recognized. So far, we used this approach to determine the goodness of different electrodes for Li‐, [8c,9] Na‐, [8c] and Al‐based [ 10 ] batteries.…”

Section: Introductionmentioning

confidence: 99%

Evaluation of MXene Ti₃C₂ Charge–Discharge Behaviors as an Electrode Material for Intercalation Batteries

Khalaj,

Shahpouri,

Khakpour

et al. 2024

Energy Tech

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“…16,22 Consequently, the time-based diagrams are very useful to compare behaviours and properties of different kinds of batteries (for instance, see the related diagrams in ref. 16 and 20). Accordingly, sketching the charge/discharge data in the time-based diagram offers some useful advantages.…”

mentioning

confidence: 97%

“…Accordingly, the goodness of the active particles can be justified. Also, evaluating the goodness of the active particles (ignoring the preparation and assembly parameters 15 ) might be a scale to assess the synthesis route. By normalization, the effect of the electrode formula (theoretical capacity, C th ) is also overcome.…”

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confidence: 99%

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Normalization of charge/discharge time vs. current rate diagrams for rechargeable batteries

Shahpouri,

Abavi-Torghabeh,

Kalantarian

et al. 2024

Phys. Chem. Chem. Phys.

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Inherent Behavior of Electrode Materials of Lithium‐Ion Batteries

Safaeipour,

Shahpouri,

Kalantarian

et al. 2024

ChemPlusChem

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For independency from the fossil fuels and to save environment, we need to move toward the green energies, which requires better energy storage devices, especially for usage in electric vehicles. Li‐ion and beyond‐lithium insertion batteries are promising to this aim. However, they suffer from some inherent limitations which must be understood to allow their development and pave the way to find suitable energy storage alternatives. It is found that each positive or negative electrode material (cathode or anode) of the intercalation batteries has its own behavioral (charge‐discharge) properties. The modification of preparation parameters (composition, loading density, porosity, particle size, etc.) may improve some aspects of the electrode performance, but cannot change the intrinsic property of the electrode itself. Accordingly, these properties are called as the “inherent behavior characteristics” of the active material. It is concluded that the behavior of a specific electrode substance, even following different preparation routes, depends only on diffusion mechanisms. This work shows that the inherent electrode properties can be visualized by representation of current density vs. capacity.

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A systematic evaluation of charge-discharge behaviors, performance, and rate-capability of Al-ion batteries

Cited by 17 publications

References 41 publications

Evaluation of MXene Ti₃C₂ Charge–Discharge Behaviors as an Electrode Material for Intercalation Batteries

Evaluation of MXene Ti₃C₂ Charge–Discharge Behaviors as an Electrode Material for Intercalation Batteries

Normalization of charge/discharge time vs. current rate diagrams for rechargeable batteries

Inherent Behavior of Electrode Materials of Lithium‐Ion Batteries

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A systematic evaluation of charge-discharge behaviors, performance, and rate-capability of Al-ion batteries

Cited by 17 publications

References 41 publications

Evaluation of MXene Ti3C2 Charge–Discharge Behaviors as an Electrode Material for Intercalation Batteries

Evaluation of MXene Ti3C2 Charge–Discharge Behaviors as an Electrode Material for Intercalation Batteries

Normalization of charge/discharge time vs. current rate diagrams for rechargeable batteries

Inherent Behavior of Electrode Materials of Lithium‐Ion Batteries

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Product

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Evaluation of MXene Ti₃C₂ Charge–Discharge Behaviors as an Electrode Material for Intercalation Batteries

Evaluation of MXene Ti₃C₂ Charge–Discharge Behaviors as an Electrode Material for Intercalation Batteries