A Systematic Study on Au-Capped Si Nanowhiskers for Size-Dependent Improved Biosensing Applications

Abstract

Reducing the distance between the fluorescence molecules and noble metal (resonant) nanostructures is known to advance the process of electromagnetic coupling and energy transfer, which in return yields fluorescence enhancement particularly exploited for improved biomedical applications. In this study, Au-capped Si nanowhiskers (NWs) at various sizes were fabricated using a vapor-liquid-solid (VLS) mechanism for systematically investigating the dependence of the size of the Au-capped Si NWs on the fluorescence enhancement factor with respect to the fluorescence emission from Rhodamine 6G (Rh-6G) fluorophore.Opposite to what is anticipated from the literature, the maximum enhancement was obtained for the sample for which the Aunanoparticle (NP) capping is well isolated from the fluorophore and the vertical distance between the fluorophore and the plasmonic metal nanoparticle is largest. Numerical simulations using the finite element method (FEM) were shown to support the experimental optical response results. Four-point probe I-V measurements also show that the Schottky ideality factor of Aucapped Si NWs decays exponentially upon the rise in the fluorescence enhancement factor.

Synthesis Methods and Optical Sensing Applications of Plasmonic Metal Nanoparticles Made from Rhodium, Platinum, Gold, or Silver

“…FEM is generally known to be more efficient for electromagnetic problems with complex nanostructures [42,43]. It has been used to study far-and near-field optical properties of metal nanostructures with complex geometry [44,45], as well as to design nanoparticle structures for metal-enhanced fluorescence [46,47] and for SERS [48], metal-insulator-metal (MIM) waveguide for refractive index sensing applications [49], and bio-related applications, e.g., hyperthermia [50], photothermal therapy [51,52], and hydrolysis [53]. There is also the discrete dipole approximation (DDA) method.…”