The effects of ageing and hydrogen charging on the notch tensile properties and fracture behaviour of individual heat-affected zones (HAZ) and Ni-based weld metal (Ni WM) of T91/TP316H weldments were investigated. After the post-weld heat treatment at 750 °C for 1 h the weldments were annealed at 600 °C for 1000 h and 5000 h, respectively. All heat-treated states were studied in condition without as well as with hydrogen charging. Thermal expositions led to additional precipitation and microstructure coarsening but their influence on tensile strength was insignificant. In contrast, remarkable plasticity decrease and the fracture mode transition from ductile dimple tearing to transgranular cleavage were observed. The combined effects of thermal exposure and hydrogen charging were more complex. Whereas the regions of Ni WM and TP316H HAZ did not show any significant change in strength, the hydrogen effect caused the strength increase in T91 HAZ. Although the hydrogen embrittling effects were clearly manifested by decreasing plasticity, their significance was getting smaller with increasing annealing duration. The fracture behaviour of thermally exposed and hydrogen charged regions exhibited mixed fracture modes including transgranular cleavage, intergranular dimple fracture and intergranular decohesion.