High partial waves for pp and np elastic scattering are examined critically from 210 to 800 MeV. Non-OPE contributions are compared with predictions from theory. There are some discrepancies, but sufficient agreement that values of the πNN coupling constants g 2 0 for π 0 exchange and g 2 c for charged π exchange can be derived. Results are g 2 0 = 13.91 ± 0.13 ± 0.07 and g 2 c = 13.69 ± 0.15 ± 0.24, where the first error is statistical and the second is an estimate of the likely systematic error, arising mostly from uncertainties in the normalisation of total cross sections and dσ/dΩ.