Absolute rate constants for the reactions of CH(X2II) with NO, N2O, NO2 and N2 at room temperature

The CH + N2 Association Reaction at Low Temperatures: Ab Initio MO/VRRKM-Theory Analysis of Temperature and Pressure Effects

“…results in a form of modified Arrhenius expressions, not including contributions from the H + NCN channel, which would be valid for the temperature region 200-1000 K. [9]; open square, [29]; crosses, [2]; open circles, [5]; filled circles, [6]; down triangles, [7]; dotted curve, [10].…”

“…Plot of the pressure dependence of the CH + N 2 association rate constant for temperatures of 52-54 K and 294-300 K. The solid curves denote VRRKM result at the E, J -resolved level; the dotted curve corresponds to VRRKM result at the E-resolved level. Experimental data: open circles, [5]; filled circles, [6]; crosses, [2]; open squares, [8]; filled squares, [9]; open triangles, [4]; stars, [10]; open diamonds, [29].…”

Combustion Chemistry of Nitrogen

“…Experimental data on this reaction are shown in Figure 2.57. Several groups have measured the rate at room temperature (Butler et al 1981;Wagal et al 1982;Lichtin et al 1984;Okada et al 1993), while two groups have measured the rate over extended ranges of low temperatures (Berman et al 1982;Becker et al 1993). There is only one direct high-temperature measurement .…”

Kinetics of the reaction CH + N2 rarr;[M]?[M] products in the range 10-620 torr and 298-1059 K

“…Accordingly, several experiments have been carried out to study the kinetics of the reaction of CH radicals with molecular nitrogen in detail. Wagal and co-workers [4] found the CH + N2 reaction to be pressure dependent in the range 10-100 torr at room temperature. The first detailed study of the CH + N2 reaction was carried out by Berman and Lin [ 5 ] .…”