2019
DOI: 10.1016/j.molliq.2019.111804
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AC/DC conductivity and dielectric relaxation behavior of ionic solutions of 1-butyl-3-methylimidazolium chloride in methanol

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Cited by 19 publications
(3 citation statements)
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“…The conductance of all analyzed fluids at a frequency of 1kHz is in the range below 1 mS, while at frequencies of 200 kHz, these values are in the range from 2 mS to 15 mS (see Fig 7a ). The conductance value increases as ion concentration increases due to a greater degree of ionic dissociations [ 33 ]. In addition, lower charge accumulations occurring around the electrodes at a higher frequency may lead to an increasing number of mobile ions.…”
Section: Resultsmentioning
confidence: 99%
“…The conductance of all analyzed fluids at a frequency of 1kHz is in the range below 1 mS, while at frequencies of 200 kHz, these values are in the range from 2 mS to 15 mS (see Fig 7a ). The conductance value increases as ion concentration increases due to a greater degree of ionic dissociations [ 33 ]. In addition, lower charge accumulations occurring around the electrodes at a higher frequency may lead to an increasing number of mobile ions.…”
Section: Resultsmentioning
confidence: 99%
“…When the frequency increases, the dipole rotational contribution becomes greater and ε follows the Maxwell Boltzmann statistics [9]. As the frequency increases, the dielectric response decreases due to the difficulty of the ions to follow the electromagnetic vibrations.…”
Section: Resultsmentioning
confidence: 99%
“…When the temperature is over 40 • C, the ohmic region of pure [BMPyrr][TFSI] is outside of the studied region, so it is not possible to obtain the ionic conductivity by the applied method, making it necessary to enlarge the frequency range to over 1 MHz. When the frequency increases, the dipole rotational contribution becomes greater and 𝜺′ follows the Maxwell Boltzmann statistics [9]. As the frequency increases, the dielectric response decreases due to the difficulty of the ions to follow the electromagnetic vibrations.…”
Section: Resultsmentioning
confidence: 99%