The spinel ferrite systems NiFe 2Àx Cr x O 4 (with x ¼ 0.0-1.0 in step of 0.2) were prepared by wet chemical co-precipitation method, using sulphates of respective metal ions. Formation of single phase spinel crystal structure of sample has been confirmed by X-ray diffraction method. Magnetic parameters such as coercivity and saturation magnetization are measured by employing vibrating samples magnetometer (VSM). The saturation magnetization and magneton number (n B ) decreases with increase in Cr 3þ content x. The Mössbauer spectra taken at 300 K and spectra are assigned to two strongly overlapping sextets corresponding to tetrahedral A sites and octahedral B sites. The cation distribution of ferrites system has been calculated by X-ray method, the behaviour of magnetization curve and Mössbauer spectra. The evaluation of cation distribution indicates that, in Cr-dominant region, few nickel ions occupies tetrahedral A sites which convert perfect inverse spinel to partially normal spinel structure.