Acid decomposition reactions of diperoxo(amine)chromium(IV) complexes

Abstract

Supplementary Material Available: Tables SI and SII, listing electronic absorption spectra and 13C NMR data, respectively, for nickel(II) compounds (2 pages). Ordering information is given on any current masthead page.

Synthesis and characterization of new bis(1-aryliminomethylenylnaphthalen-2-oxy)nickel complexes and their catalytic behavior for vinyl polymerization of norbornene

“…All ligands were synthesized via the condensation of 2-hydroxy-1-naphthaldehyde with phenylamines or pyridinylamines with protocols reported in the literatures [23][24][25][26][27][28][29][30][31][32][33].…”

“…Ligand L16 was prepared with a protocol described in the literature [30], and was obtained as yellow microcrystals. Yield 0.58 g (89.0%).…”

“…Yield 0.58 g (89.0%). [30] Ligand L17 was prepared from the condensation of 2-hydroxy-1-naphthaldehyde with 2-amino-4,6-dimethylpyridine using the above protocol for L14, and was obtained as yellow crystals. Yield 0.58 g (83.7%), m.p.…”

Oxidation Kinetics of D-Ribose by µ- Peroxo Complex in Aqueous Medium

“…The products formed in the second step release activated oxygen with the concurrent reduction of mononuclear Co(III) complex to mononuclear Co(II) complex. This step supported by the mechanism which gives release of oxygen from a µ-peroxo complex Co(III) dimer [15]. The activated oxygen reacts with the substrate and gives the product in the final step.…”

Synthesis, characterization and charge-transfer photochemistry of trans-aquo azido-N,N?-trimethylenebis(naphthylideneiminato)chromium(III)

“…In particular, chromium(V) chemistry has received more attention in recent times due to its use as inorganic and organic oxidants [7]. As part of our efforts to stabilize the unusual oxidation state like chromium(IV) and chromium(V) [8,9], we carried out the synthesis of a few chromium(III) Schiff base complexes [10,11]. The photolysis of chromium(III) azides has been reported to produce Ôcoordinated nitreneÕ complexes [12,13] as shown in the following equation, ½Cr III ðLÞðN 3 ÞðH 2 OÞ À!…”