Acidic‐basic interactions in tungstate melts based on tungsten electroplating out of them

Abstract

Based on thermodynamic calculations of possible reactions of interaction between sodium tungstate and oxygen-containing compounds of boron, carbon, phosphor, sulphur, metals of VI-B group the probability of possible reactions was evaluated. The experimental verification of the assumptions was accomplished by the methods of potentiometry and IR-spectroscopy. The possibility of existence of equilibrium (reversible) melted systems with the electrodes from metals of VI-B group and their carbides was proved by the electrochemical measurements and thermodynamic calculations.

Nanostructured rhodium: electrochemical behaviour and electrodeposition from low‐temperature carbamide‐ and acetamide‐containing melts

“…Nanoparticles and materials on their basis show unique electrical, chemical, magnetic, optical, catalytic and other properties; therefore a lot of attention has been paid to these researches . Moreover, nanocomposite materials have been widely utilized in modern technologies and materials science, thus the methods of their synthesis have also been developed .…”