Ensuring
material performance reliability and lifetime is crucial
for practical operations. Small cracks on the material surface are
often detrimental to its safe operation. This study describes the
development of a hydrogen bond-rich puncture-resistant polyurethane
elastomer with supertoughness. The as-prepared polyurethane transparent
films feature high tensile break strength (57.4 MPa) and great toughness
(228 MJ m–3). Additionally, a facile, low-cost,
crack self-diagnostic approach through photoluminescence using a small
luminous pen is reported. The materials efficiently achieved self-healing
at 90 °C after the crack formation. The change of fluorescence
intensity on the crack can be used to track the self-healing process.
Therefore, this work provides a guideline for the material design
of supertough, puncture-resistant, transparent, and healable elastomers
and a crack self-diagnosis and healing approach.