The electronpar~,,agneticresonance(E~n) ofan Mn2+ (S = 5/2)impurityin thefvroelasticandpars,el~ticphaseof BiVOa aystab withaein&domain. grown by the Czodrralrki method, has been investigated using an X-band spectrometer. The rotatimpattansof theresouanceficldsmeasdon the crystallographic.094 f 0.002, B:/h = 0.0, A=/IL = 0.27f 0.02, A,/h = 0.25 f 0.02, and A,/h=093fO.O2GHzatroomtnnnpraatre((< T, = 5 2 8 K ) ; m d g = 1.994f0.001, D/h = 0.000 f 0.004, E / h = 0.000 f 0.004, F / h = 0.00 & 0.01, A / h = 0.25 f 0.01 GHz at T = 535 K (> TC). The principal 2. y, and z axes of the D-tensor are foundto be along the crystallographic 6, c + 45' and Z + 45' axes, respectively. This fiz+ a n t r e has the correct principal axes system of the D-tensor compsred with the previous Miq centre. The D-value deueases as the temperature increases in the range 107-535 K. It is proposed that the Mn*+ ion substitutes for Bi3+ without nearby charge compemation.