Acridin-9(10H)-one based thermally activated delayed fluorescence emitter for highly efficient green OLED

Xu, Min; Li, Jiuyan; Liu, Di; Mei, Yongqiang; Liu, Botao; Wu, Qi; Li, Yixue; Wang, Jiahui; Wan, Huihui

doi:10.1016/j.dyepig.2023.111503

Dyes and Pigments

2023

DOI: 10.1016/j.dyepig.2023.111503

|View full text |Cite

Acridin-9(10H)-one based thermally activated delayed fluorescence emitter for highly efficient green OLED

Min Xu

Jiuyan Li

Di Liu

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 35 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Thermally Activated Delayed Fluorescence Emitters Based on Rigid Lactam Acceptors: Simultaneously Achieving Desirable Emission Efficiency, Horizontal Orientation, and Reverse Intersystem Crossing

Wu,

Sun,

et al. 2024

Adv Funct Materials

View full text Add to dashboard Cite

Thermally activated delayed fluorescence (TADF) materials that exhibit simultaneously high photoluminescence quantum yield (PLQY), rapid reverse intersystem crossing (RISC), and a high horizontal transition dipole ratio are highly desirable for realizing high‐performance organic light‐emitting diodes (OLEDs). However, achieving this goal remains a formidable challenge due to the stringent molecular design principles involved. Herein, three highly efficient TADF materials based on lactam‐type electron‐acceptors are reported. The inherent rigidity and planar structure of lactam units, along with the ordered molecular arrangement in solid states, contribute to the reduction of nonradiative decay and the high horizontal transition dipole ratio in the optimized TADF emitters. Moreover, through precise control of the alignment of the lowest excited states by adjusting the charge transfer strength, the rate constants for reverse intersystem crossing (kRISC) are dramatically boosted. Consequently, the two optimized emitters exhibit outstanding merits of ultra‐high PLQYs (98% and 99%), high horizontal transition dipole ratios (91% and 87%), and fast RISC (kRISC ≈ 1.7 × 106 s−1). Thanks to these merits, the doped OLEDs achieve excellent performance. The top‐performing device achieve a maximum external quantum efficiency of 34.3%, a peak luminance of 57376 cd m−2, and small efficiency roll‐off.

show abstract

Thermally Activated Delayed Fluorescence Emitters Based on Rigid Lactam Acceptors: Simultaneously Achieving Desirable Emission Efficiency, Horizontal Orientation, and Reverse Intersystem Crossing

Wu,

Sun,

et al. 2024

Adv Funct Materials

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Acridin-9(10H)-one based thermally activated delayed fluorescence emitter for highly efficient green OLED

Cited by 1 publication

References 35 publications

Thermally Activated Delayed Fluorescence Emitters Based on Rigid Lactam Acceptors: Simultaneously Achieving Desirable Emission Efficiency, Horizontal Orientation, and Reverse Intersystem Crossing

Thermally Activated Delayed Fluorescence Emitters Based on Rigid Lactam Acceptors: Simultaneously Achieving Desirable Emission Efficiency, Horizontal Orientation, and Reverse Intersystem Crossing

Contact Info

Product

Resources

About