Acrylic coatings exhibiting improved hardness, solvent resistance and glossiness by using silica nano-composites

Dashtizadeh, Ahmad; Abdouss, Majid; Mahdavi, Hossein; Khorassani, Manuchehr

doi:10.1016/j.apsusc.2010.09.060

Cited by 78 publications

(39 citation statements)

References 24 publications

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“…larger Persoz hardness numbers. Relatively higher hardness values of microcapsules embedded coating samples revealing the formation of harder coating films [23,24]. This increase in hardness was consistent with the increase of modulus.…”

Section: Mechanical Properties Of Acrylic Coating Containing Microcapsupporting

confidence: 85%

Mechanical and self-healing properties of a water-based acrylic latex containing linseed oil filled microcapsules: Effect of pre-silanization of microcapsules' shell compound

Es-haghi

Mirabedini

Imani

et al. 2016

Composites Part B: Engineering

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Section: Mechanical Properties Of Acrylic Coating Containing Microcapsupporting

confidence: 85%

Mechanical and self-healing properties of a water-based acrylic latex containing linseed oil filled microcapsules: Effect of pre-silanization of microcapsules' shell compound

Es-haghi

Mirabedini

Imani

et al. 2016

Composites Part B: Engineering

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“…The abrasion resistance of AP2S5 is about 42% more than that of AP1S5 because of the interaction which takes place between the functional groups of AAm monomers and silica aerogel. In fact, the abrasion resistance of the samples is affected by the hardness of the coatings …”

Section: Resultsmentioning

confidence: 99%

“…The acrylic polymers and copolymers possess unique combination of the properties such as excellent weather ability, great resistance to abrasion, water and cracks and also low thermal conductivity which is a key parameter for thermal insulators. Some investigations have focused on improving the mechanical properties of the acrylic resins with various additives such as silica nano‐particles, fly ash, glass fiber, and woven electrical glass fibers (E‐glass fiber) . Delmonico fabricated an insulating paint for interior and exterior of buildings including hollow glass extender or glass microspheres.…”

Section: Introductionmentioning

confidence: 99%

Improvement of thermal properties of pigmented acrylic resin using silica aerogel

Karami

Motahari

Eskandari

2017

J of Applied Polymer Sci

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In this study, two different types of acrylic resins were synthesized through emulsion polymerization. The first category of acrylic resins contained methyl methacrylate, 2-ethylhexyl acrylate, and acrylic acid monomers. The second composition had an additional monomer named acrylamide (AAm). The kinetic behavior of polymerization reaction was investigated. The results showed that the presence of the AAm monomer increased the monomer conversion (>90% in the first 10 min) and the rate of polymerization. Furthermore, the latexes were characterized by Dynamic Light Scattering (DLS) Fourier Transform Infrared, and differential scanning calorimeter analysis. To study the effect of silica aerogel as a thermal barrier additive for acrylic resins, samples were mixed with silica aerogel using sodium dodecyl sulfate as a surfactant. In the next step, the above-mentioned resins were used to make white acrylic-based paints. The heat transfer measurements revealed that the thermal insulation properties were not affected by the composition of the resin. On the other hand, the use of AAm monomer increased the paint adhesion properties and helped the resin to receive more aerogel (up to 5 wt %) which in turn decreased the heat loss of the painted wall.

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“…In recent decades, water‐based coatings have been more and more popular in coatings industry due to the environmental pollution, resource waste, and high costs of solvent‐based coatings . And commercial water‐based emulsion latex could be widely accessed in preparing water‐based coatings nowadays.…”

Section: Introductionmentioning

confidence: 99%

Facile Fabrication of Superhydrophobic Nanocomposite Coatings Based on Water‐Based Emulsion Latex

Yang

Liang

Zeng

et al. 2018

Adv Materials Inter

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become an outstanding strategy to fabricate superhydrophobic coatings.Generally, polymer/inorganic superhydrophobic composite coatings are prepared by incorporating modified inorganic nanofillers into polymer resin. Inorganic nanofillers modification is a good way for evenly dispersing inorganic-organic phase due to the improved interfacial compatibility. As it has been demonstrated that surface chemical composition and surface topography act synergistically to construct superhydrophobic surface. [13] The inorganic nanofillers used here are normally modified with hydrophobization reagents, which will promote the superhydrophobicity on the coating surface. Recent progress has developed a myriad of hydrophobic inorganic nanomaterials, for example, fluorinated multiwalled carbon nanotubes, [14] oligodimethylsiloxane modified fumed silica nano particles, [15] and fluorinated silica nanoparticles. [16] Poly mer/inorganic superhydrophobic coatings possessing excellent water-repellent properties could be obtained after the hydrophobic inorganic nanofillers being introduced into poly mer resin. However, to dissolve the polymer resin and disperse hydrophobic inorganic nanofillers evenly, VOCs such as acetone, tetrahydrofuran, and toluene were required to prepare the dispersion, which would lead to severe environment problems. Thus, these drawbacks remarkably hold up the practical applications of the superhydrophobic composite coatings.In recent decades, water-based coatings have been more and more popular in coatings industry due to the environmental pollution, resource waste, and high costs of solvent-based coatings. [17] And commercial water-based emulsion latex could be widely accessed in preparing water-based coatings nowadays. However, low surface energy materials especially hydrophobic modified inorganic materials are difficult to disperse in water, thus only limited studies of water-based superhydrophobic coating systems have been reported. [18] For instance, Zhou et al. reported using a stable dispersion of polytetrafluoroethylene (PTFE) nanoparticles, fluorinated alkylsilane and fluorocarbon surfactant to prepare superamphiphobic surface, in which the similar fluoroalkyl chain in abovementioned ingredients synergistically played an important role. [18a] The other methods mostly introduced hydrophilic nanofillers in water-based systems. For example, Schutzius et al. developed a superhydrophobic coating via polyolefin blend dispersion and exfoliated graphite nanoplatelets under alkaline conditions. [18b] MatesTo prepare water-based superhydrophobic coatings with excellent properties would be of great significance, but it remains difficult to solve the problems of uneven dispersion of hydrophobic modified inorganic nanofillers in water and poor interfacial compatibility between hydrophilic inorganic nanofillers and polymer matrix in the film. Herein a novel and green technology is reported to disperse dodecyltriethoxysilane in water-based polymer system uniformly by adsorbing it on the surface of emulsion latex part...

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Acrylic coatings exhibiting improved hardness, solvent resistance and glossiness by using silica nano-composites

Cited by 78 publications

References 24 publications

Mechanical and self-healing properties of a water-based acrylic latex containing linseed oil filled microcapsules: Effect of pre-silanization of microcapsules' shell compound

Mechanical and self-healing properties of a water-based acrylic latex containing linseed oil filled microcapsules: Effect of pre-silanization of microcapsules' shell compound

Improvement of thermal properties of pigmented acrylic resin using silica aerogel

Facile Fabrication of Superhydrophobic Nanocomposite Coatings Based on Water‐Based Emulsion Latex

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