Grid multi-scroll/wing chaotic systems are complex non-linear dynamic systems, which are widely used in secure communication. The grid multi-scroll/wing chaotic systems are usually realized by using the function control method, which has a complex realization method, many control parameters, and a simple unit attractor structure. In this paper, based on the Hopfield neural network, a memristive Hopfield neural network model is proposed by using the memristor synapse control method. The model can generate novel grid multi-structure chaotic attractors, which have the characteristics of a simple implementation method, few control parameters, and complex unit attractor structure. Firstly, the generation mechanism of the grid multi-structure chaotic attractors is analyzed by the equilibrium points and stability. Secondly, its basic dynamical characteristics including the Lyapunov exponent spectrum, fractal dimension, time series, power spectrum, bifurcation diagram, and Poincaré section are analyzed. Thirdly, an analog circuit of the neural network model is designed and realized by Multisim. Finally, combined with the chaos encryption principle, an image encryption scheme is designed based on the generated grid multi-structure attractors. Experimental results show that compared with the existing schemes, the proposed scheme has larger information entropy, higher key sensitivity, and a good application prospect.