Addition of [CH(CN)2]− and [TCNE]˙− to RuVIN bearing 8-quinolinolato ligands

Leung, Chi‐Fai; Yiu, Shek‐Man; Xiang, Jing; Lau, Tai‐Chu

doi:10.1039/c0cc01645d

Cited by 5 publications

(1 citation statement)

References 23 publications

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“…12 24), diimine/imino-oxazolone ( 25) complexes, respectively (Scheme 8). 109 The Ru VI -nitrido complex [Ru(N)(Cl)(L 3 )] ( 26), (L 3 = N-salicylidene-o-aminophenol), with a tridentate Schiff base reacts with excess cyanide to produce a tricyanoruthenium(III) complex (27), in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred (Scheme 9). 103 Ru VI -nitrido species with tetradentate Schiff base ligands often exhibit strong electrophilic properties, and undergo a variety of redox reactions that are initiated by nucleophilic attack at the nitrido ligand.…”

Section: Ru VI -Nitrido Complexesmentioning

confidence: 99%

Recent developments in ruthenium nitrido complexes

Liang

2013

RSC Adv.

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Metal nitrido complexes are frequently invoked as key intermediates in numerous synthetic, catalytic and enzymatic transformations, such as C-N and H-N bond-formation, nitrogen atom/group transfer reactions and biological nitrogen fixation by nitrogenase enzyme. Ruthenium nitrido complex is one of the most important metal nitrido complexes. There is a growing interest in chemistry of Ru-nitride. Over the past decade, numerous chemically activated ruthenium nitrido complexes have been discovered. This short review summarizes recent advances in the synthesis and reactivity of these complexes.

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Section: Ru VI -Nitrido Complexesmentioning

confidence: 99%

Recent developments in ruthenium nitrido complexes

Liang

2013

RSC Adv.

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Coordination Chemistry of Metal Phenolates—General Aspects

Doerrer

2014

Patai's Chemistry of Functional Groups

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An overview of metal phenolate chemistry is given that highlights the structural and functional diversity of contemporary chemistry between metals from all parts of the periodic table and aryloxide ligands. After a brief overview of synthetic methods, the review is organized using structural characterization, but is not exclusive of non‐structurally characterized species. Monodentate and polydentate ligands are described and organized by the type and number of donor atoms. Within each section, the chemistry is further subdivided by the periodic table s‐, p‐, d‐, and f‐blocks. Extensive references to the literature are provided for the interested reader.

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Reactive Transition Metal Nitride Complexes

Smith

2014

Progress in Inorganic Chemistry

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Addition of [CH(CN)2]− and [TCNE]˙− to RuVIN bearing 8-quinolinolato ligands

Abstract: Reaction of Ru(VI)≡N complexes bearing 8-quinolinolato ligands with NCCH(2)CN/piperidine and NaTCNE afford novel ruthenium(ii) dicyanoimine and diimine/imino-oxazolone complexes, respectively.

Cited by 5 publications

References 23 publications

Recent developments in ruthenium nitrido complexes

Recent developments in ruthenium nitrido complexes

Coordination Chemistry of Metal Phenolates—General Aspects

Reactive Transition Metal Nitride Complexes

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