“…The choice of photoinitiators plays an essential role in vat photopolymerization where selection depends on the specific resin and printing conditions [ 84 ]. Literature search results indicate that diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (TPO), ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate(TPO-L), and phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide (BAPO) are commonly used as photoinitiators for preceramic materials [ 85 , 86 , 87 , 88 , 89 , 90 , 91 , 92 , 93 , 94 , 95 ], and Figure 7 a illustrates their chemical structures. TPO, TPO-L, and BAPO belong to the Norrish type I category, which can effectively generate free radicals through homolytic cleavage of their C-O or C-N bonds upon exposure to light radiation [ 82 ].…”