2022
DOI: 10.1080/17452759.2022.2150230
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Additive manufacturing of flexible polymer-derived ceramic matrix composites

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Cited by 14 publications
(4 citation statements)
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“…The choice of photoinitiators plays an essential role in vat photopolymerization where selection depends on the specific resin and printing conditions [ 84 ]. Literature search results indicate that diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (TPO), ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate(TPO-L), and phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide (BAPO) are commonly used as photoinitiators for preceramic materials [ 85 , 86 , 87 , 88 , 89 , 90 , 91 , 92 , 93 , 94 , 95 ], and Figure 7 a illustrates their chemical structures. TPO, TPO-L, and BAPO belong to the Norrish type I category, which can effectively generate free radicals through homolytic cleavage of their C-O or C-N bonds upon exposure to light radiation [ 82 ].…”
Section: Additive Manufacturing For Preceramic Polymersmentioning
confidence: 99%
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“…The choice of photoinitiators plays an essential role in vat photopolymerization where selection depends on the specific resin and printing conditions [ 84 ]. Literature search results indicate that diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (TPO), ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate(TPO-L), and phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide (BAPO) are commonly used as photoinitiators for preceramic materials [ 85 , 86 , 87 , 88 , 89 , 90 , 91 , 92 , 93 , 94 , 95 ], and Figure 7 a illustrates their chemical structures. TPO, TPO-L, and BAPO belong to the Norrish type I category, which can effectively generate free radicals through homolytic cleavage of their C-O or C-N bonds upon exposure to light radiation [ 82 ].…”
Section: Additive Manufacturing For Preceramic Polymersmentioning
confidence: 99%
“…Excessive fillers may lead to decreased quality of the final product with increased porosity and reduced mechanical properties, primarily due to decreased continuity of the matrix phase [ 113 ]. Recently, scientists from the same research group introduced another photosensitive preceramic formulation by mixing polysilazane, vinyltrimethoxysilane, aliphatic urethane acrylate, TPO, Sudan III, and a certain amount of ɑ-Si 3 N 4 nanopowder (0–40 wt.%) as an inert filler to make solid structures using DLP [ 85 ]. The flexible 3D printed green structures could be transformed into various shapes, and after pyrolysis, they yielded ceramic nanocomposites while retaining the initial shapes and structures, as presented in Figure 10 .…”
Section: Additive Manufacturing For Preceramic Polymersmentioning
confidence: 99%
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“…The application of numerous primary procedures can be broken down into categories such as slurry preparation, printing and forming, drying and sintering, sanding or postprocessing, etc. [11,12]. The extrusion molding principle describes how the ceramic material is made to have specific mobility by adding solvents or heating it physically after it has been extruded externally to a specific caliber (often hundreds of microns to a few millimeters in diameter).…”
Section: Introductionmentioning
confidence: 99%