“…The loss function presented in (1) was used for training the transformation model as well. Owing to the sparse nature of LIBS spectra 87 every layer of the model was regularized. The same ReLU activation function was used here as well.…”
Laser-induced breakdown spectroscopy (LIBS) is a well-established analytical tool with relevance in extra-terrestrial exploration. Despite considerable efforts towards the development of calibration-free LIBS approaches, these are currently outperformed by calibration-based...
“…The loss function presented in (1) was used for training the transformation model as well. Owing to the sparse nature of LIBS spectra 87 every layer of the model was regularized. The same ReLU activation function was used here as well.…”
Laser-induced breakdown spectroscopy (LIBS) is a well-established analytical tool with relevance in extra-terrestrial exploration. Despite considerable efforts towards the development of calibration-free LIBS approaches, these are currently outperformed by calibration-based...
“…The sparsity of LIBS samples relative to the number of discrete wavelength datapoints (here n = 339) is a challenge in postacquisition processing of data. 6 Since we are using higherorder singular value methods which require that data matrices have full rank, our approach to the sparsity problem is the statistical method of bootstrapping. 4,5,7,8 Bootstrapping is a technique in sampling to create additional representative samples from a given dataset in a statistically controlled way.…”
Section: Addressing Sparsity In Libs Data By Bootstrappingmentioning
The standard uranium enrichment approach uses centrifuges to separate 235U [Uranium 235] and 238U [Uranium 238] in the gaseous form, UF6 [uranium hexafluoride]. Laser-induced breakdown spectroscopy (LIBS) is gaining acceptance...
“…LIBS spectra are considered to exhibit high dimensionality, redundancy, and sparsity. In this context, Képeš et al 140 proposed the use of sparse PCA for the analysis of high-dimensional sparse data , significantly improving the interpretability of loading spectra. The randomised algorithm was demonstrated to offer a 20-fold increase in computation speed compared to PCA based on singular value decomposition.…”
This review covers advances in atomic spectrometric techniques, including atomic emission, absorption, fluorescence and mass spectrometry. Material on speciation and coupled techniques is not covered as this is included in a separate ASU review.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.