“…Coatings to be used in harsh environments and with high mechanical properties at elevated temperatures are of great importance for the advancement of power generation technologies, such as in pressure tubes in thermal and nuclear power plants, in chemical factories, in the oil gas generation industry, and inside boilers where waste and biomass are used (Ref 331 ). Cost effective and thick coatings of nickel-based superalloys (Ref 332 , 333 ), steel and stainless steel alloys (Ref 334 - 336 ), titanium alloys (Ref 337 , 338 ), tantalum (Ref 339 , 340 ), and niobium (Ref 341 , 342 ) have been produced using several thermal spray processes, such as HVOF, HVAF, APS,WAS, and TWAS (Ref 333 , 334 , 336 , 337 , 343 , 344 ). They are usually characterized by a high-oxide content (Ref 334 , 336 , 339 , 345 ), high porosity levels (Ref 334 , 337 , 340 , 344 - 346 ), and micro-cracks (Ref 343 , 345 , 346 ).…”