Adsorption dynamics of methyl violet onto granulated mesoporous carbon: Facile synthesis and adsorption kinetics

Kim, Young S.; Bae, Jiyeol; Park, Hosik; Suh, Jeong-Kwon; You, Young-Woo; Choi, Heechul

doi:10.1016/j.watres.2016.04.077

Cited by 71 publications

(22 citation statements)

References 47 publications

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“…This constancy of adsorption capacity, i.e., reaching the equilibrium point within duration longer than 60 min might be due to saturation of active sites on the surface of the adsorbent or completion of the adsorbent capacity (Satilmis and Budd 2017). Similar effects were observed by other researchers for contact time on the dye removal by different adsorbents (Kim et al 2016;Konicki et al 2017).…”

Section: Effect Of Contact Timesupporting

confidence: 90%

“…It is confirming that adsorption rate decreased with the increase in initial dye concentrations as observed by the effect of contact time study (Kumari et al 2017). The kinetics of adsorption of many dye species onto various biosorbents was also found to be of pseudo-second-order in the literature: reactive orange 16 adsorption in carbonized fish scales (Marrakchi et al 2017), reactive orange 16 on chitosan (Marrakchi et al 2016), reactive orange 16 adsorption on brewery yeast (Kim et al 2016).…”

Section: Adsorption Kineticsmentioning

confidence: 84%

“…The constant of the number of active sites on the adsorbent versus the increase in the number of the molecules of the adsorbent or saturation of the adsorbent surface at high concentrations (Kim et al 2016). The increase in dye concentration causes an increase in the driving force between the solution and biosorbent and hence the mass transfer resistance between the dye and the psyllium is reduced leading to an increase in the biosorption capacity (Kumari et al 2017).…”

Section: Effect Of Initial Dye Concentrationmentioning

confidence: 99%

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Reactive orange 16 dye adsorption from aqueous solutions by psyllium seed powder as a low-cost biosorbent: kinetic and equilibrium studies

Malakootian

Heidari

2018

Appl Water Sci

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The biosorption process using natural materials has found widespread applications than to their inexpensiveness, availability, and reusability. The aim of this research is to investigate the efficiency of psyllium seed powder in removal of reactive orange 16 dye. The impacts of various influential parameters such as initial pH, contact time, adsorbent dose, temperature and dye concentration were evaluated using a batch biosorption method. Data analysis was conducted by SPSS 19. The removal efficiency of reactive dye 16 using the natural adsorbent psyllium was obtained to be 94% in optimal conditions (pH 4, contact time = 40 min, and adsorbent dose = 2 g/L). Biosorption equilibrium experiments indicated that the best fit was achieved with Langmuir isotherm model. Maximum adsorption capacity was found to be 206.6 mg/g at 303 K. Kinetic analysis revealed that adsorption experimental data were best fitted by pseudo-second-order model. Free energy of adsorption (ΔG°), enthalpy (ΔH°), and entropy (ΔS°) changes were calculated to predict the nature of adsorption. Thermodynamic evaluation indicates that a spontaneous process has occurred. Inexpensive, locally available, and effective materials could be used for dye removal in wastewater treatment processes. Undoubtedly low-cost adsorbent benefits for commercial purposes in the future.

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Section: Effect Of Contact Timesupporting

confidence: 90%

Section: Adsorption Kineticsmentioning

confidence: 84%

Section: Effect Of Initial Dye Concentrationmentioning

confidence: 99%

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Reactive orange 16 dye adsorption from aqueous solutions by psyllium seed powder as a low-cost biosorbent: kinetic and equilibrium studies

Malakootian

Heidari

2018

Appl Water Sci

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“…Effective, fast dye removal is essential prior to effluent discharge 8 . Among the conventional dye-effluent treatment techniques, adsorption to a solid substrate is one of the more economical and viable methods 9,10 . Characteristics include excellent affinity towards target dye molecules, high adsorption capacities and the possibility of adsorbent regeneration influence the selection of adsorbents employed 11 .…”

Section: Introductionmentioning

confidence: 99%

Dye-Mediated Interactions in Chitosan-Based Polyelectrolyte/Organoclay Hybrids for Enhanced Adsorption of Industrial Dyes

Huang

Xia

Kazlauciunas

et al. 2019

ACS Appl. Mater. Interfaces

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Non-covalent, dye-mediated interactions between organo-montmorillonites (''organo-clays'') and a chitosan-based polyelectrolyte are exploited for highly effective and fast removal of different, industrially-important anionic dyes (singleazo, double-azo, anthraquinone) from aqueous solutions. The addition of only 10 wt% of polyelectrolyte to a conventional organo-clay results in a 100% increase in absolute dye uptake capacity, an acceleration of dye uptake kinetics by up to 500%, and the flocculation of large, easily-separable sorbent aggregates. These substantial improvements in adsorption performance are driven by the mediating effect of the anionic dyes (acting as electrostatic mediator between the positively-charged polyelectrolyte chains and organo-clays), enabling the formation of true hybrid sorbent structures without the need for covalent crosslinking chemistry. The dye-mediated sorption and hybrid formation mechanism is further evidenced by structural and chemical characterization of the hybrid sorbents (small angle XRD, IR mapping) as well as by analysis of dye sorption kinetics according to the intraparticle diffusion model. Importantly, the organo-clay/polyelectrolyte hybrid system provides a highly interesting adsorbent for the treatment of dye mixtures. Our study shows that structurally different anionic dyes localise at different sites within the hybrid structure (organo-clay intergallery spaces vs polyelectrolyte/organo-clay interface), enabling the simultaneous adsorption of different dyes with high efficiency. Consequently, the total uptake capacity for dye mixtures was 50% larger than that of individual dyes, demonstrating the enormous potential of the hybrids for industrial wastewater purification, where dye mixtures are ubiquitous.

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“…Some of the advantages of the surface absorption method are its low initial cost, simple design and operation, need for much lower energy source, lack of influence of toxic materials in great removal of contaminants with organic nature compared to other conventional treatment methods and non-selective functioning (21, 23). But restrictions in surface adsorption process such as increased suspended solids in water caused by powder form applications and their difficult separation, especially carbon forms from the water environment, have caused engineers to fix these separation problems and make changes in the form of absorbent application (24). In addition, in order to reduce preparation costs, the use of inexpensive materials such as remains of crops for production biodegradable biological absorbents has been highly regarded as a potential option (25).…”

Section: Introductionmentioning

confidence: 99%

Removal of Acid Orange 7 dye from aqueous solutions by adsorption onto Kenya tea pulps; granulated shape

Naraghi¹,

Zabihi²,

Narooie³

et al. 2017

Electron physician

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Background and AimWater resources pollution control is one of the main challenges of our time for researchers. Colored wastewater discharges caused by textile industry activities has added to the concern. In this study, removal of Acid Orange 7 dye (AO7) using Kenya Tea residue absorbent (granular) has been studied.MethodsThis cross-sectional study was conducted in 2016. In this work, initially, tea residue was prepared in three forms of raw, treated with concentrated phosphoric acid, and carbonated, at temperatures of 350, 450 and 500 °C in the chemistry laboratory of Gonabad University of Medical Sciences. Then, efficiency of the above absorbents in the removal of Acid Orange 7 dye in initial concentrations of dye as 50–500 mg/l from water samples in terms of pH 2–10 and 1–10 g/l of adsorbent dose within 20 to 300 minutes was investigated. In addition, their subordination from Langmuir and Freundlich absorption isotherms was also determined. Concentration changes in Acid Orange 7 dye at a wavelength of 483 nm was determined by spectrophotometry and results were reported using descriptive statistics.ResultsResults showed that efficiency of Acid Orange 7 dye removal is higher in acidic pH and higher adsorbent dosage. The highest efficiency of Acid Orange 7 dye removal was 98.41% by raw tea residue absorbent at pH 2, reaction time was 120 minutes and initial concentration of dye was 50 mg/l, which was obtained at adsorbent dosage of 10 g/l. It was determined that the mechanism of absorption acceptably follows Freundlich absorption isotherm (R2=0.97).ConclusionDue to the availability and very low price, optimal performance of Kenya tea raw residue (granular) in Acid Orange 7 dye removal, it can be used as an efficient surface absorber in an absorber from colored wastewater.

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Adsorption dynamics of methyl violet onto granulated mesoporous carbon: Facile synthesis and adsorption kinetics

Cited by 71 publications

References 47 publications

Reactive orange 16 dye adsorption from aqueous solutions by psyllium seed powder as a low-cost biosorbent: kinetic and equilibrium studies

Reactive orange 16 dye adsorption from aqueous solutions by psyllium seed powder as a low-cost biosorbent: kinetic and equilibrium studies

Dye-Mediated Interactions in Chitosan-Based Polyelectrolyte/Organoclay Hybrids for Enhanced Adsorption of Industrial Dyes

Removal of Acid Orange 7 dye from aqueous solutions by adsorption onto Kenya tea pulps; granulated shape

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