Adsorption of antimony and arsenic from a copper electrorefining solution onto activated carbon

Navarro, Patricio; Alguacil, Francisco José

doi:10.1016/s0304-386x(02)00108-1

Cited by 137 publications

(59 citation statements)

References 8 publications

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“…These methods include cementation [110][111][112], solvent extraction [113][114][115][116][117], adsorption on activated carbon [118][119][120], and ion exchange [121][122][123][124][125][126].…”

Section: Recovery Of Precious Metals From Leachatementioning

confidence: 99%

Metallurgical recovery of metals from electronic waste: A review

Cui

Zhang

2008

Journal of Hazardous Materials

1,493

685

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Section: Recovery Of Precious Metals From Leachatementioning

confidence: 99%

Metallurgical recovery of metals from electronic waste: A review

Cui

Zhang

2008

Journal of Hazardous Materials

1,493

685

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“…This fast rate of adsorption makes this resin promising for practical applications in comparison with other reported adsorbents. The equilibrium time of some previously studied resins extends from 2 h up to few days (Navarro and Alguacil 2002;Miller and Zimmerman 2010;Goswami et al 2012). Figure 3b shows rate of Mo(V) release to the solution; it could be seen that 1.47 % of the loaded Mo(VI) is released after 6 min and Mo(V) release becomes constant after 20 min (2.56 %).…”

Section: Kineticsmentioning

confidence: 98%

Removal of arsenate from aqueous media by magnetic chitosan resin immobilized with molybdate oxoanions

Elwakeel

2013

Int. J. Environ. Sci. Technol.

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Chitosan was cross-linked using glutaraldehyde in the presence of magnetite. The resin obtained was chemically modified through the reaction with tetraethylenepentamine ligand. The obtained resin was loaded with Mo(VI) and investigated. The adsorption characteristics of the obtained resin toward As(V) at different experimental conditions were investigated by means of batch and column methods. The resin showed high affinity and fast kinetics for the adsorption of As(V) where an uptake value of 1.30 mmol g -1 was reported in 6 min at 25°C. Various parameters such as pH, agitation time, As(V) concentration and temperature had been studied. The kinetics and thermodynamic behavior of the adsorption reaction were defined. These data indicated an endothermic and spontaneous adsorption process and kinetically followed pseudosecond-order model, Fickian diffusion low and Elovich equation. Breakthrough curves for the removal of As(V) were studied at different flow rates and bed heights. The critical bed height for the studied resin column was found to be 0.656 cm at flow rate of 4 mL min -1 . The mechanism of interaction between As(V) and resin's active sites was discussed. Regeneration and durability of the loaded resin toward the successive cycles were also clarified.

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“…Qualitatively speaking, it can be found that As(III) and As(V) loadings acquired from the present study are within the ranges obtained with other metals, though differences in the type of adsorbent/ biosorbent (among other experimental conditions) utilized are of a paramount significance if quantitative comparisons must be done. Activated carbon adsorption was explored in removal of arsenic and antimony from copper electrorefining solutions [80]. A huge arsenic sorption capacity (2860 mg/g) was obtained on this coal-derived commercial carbon.…”

Section: Final Remarks On Isotherm Studymentioning

confidence: 99%

Investigation on Elimination of As(III) and As(V) from Wastewater Using Bacterial Biofilm Supported on Sawdust/MnFe2O4 Composite

Podder

Majumder

2016

Water Conserv Sci Eng

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The goal of the present research was to study the ability of Corynebacterium glutamicum MTCC 2745 immobilized on Sawdust/MnFe 2 O 4 composite to treat arsenic bearing wastewater by simultaneous biosorption and bioaccumulation (SBB) system at laboratory scale and also to investigate the influences of initial pH, biosorbent dose, contact time, temperature and initial arsenic concentration on biosorption/bioaccumulation of both As(III) and As(V). The surface texture of the immobilized bacterial cells was investigated through SEM-EDX analysis. The presence of functional groups on the surface of immobilized bacterial cells that may interact with the metal ion was confirmed by FT-IR. The pattern of biosorption/bioaccumulation fitted well with Vieth and Sladek isotherm model for As(III) and Brouers-Sotolongo and Fritz-Schlunder-V isotherm models for As(V). The maximum adsorption capacity estimated using Langmuir model was 1672.32214 mg/g for As(III) and 1861.71453 mg/g for As(V) at 30°C temperature and 240 min contact time. The results showed that As(III) and As(V) removal was strongly pH-dependent with an optimum pH value of 7.0. The effect of co-existing ions, such as Cu 2+ , Zn 2+ , Bi 3+ , Cd 2+ , Fe 3+ , Pb 2+ , Co 2+ , Ni 2+ , Cr 6+ and SO 4 2− , at different concentrations were examined. Desorption study exhibited that over 81.34 and 88.727 % could be desorbed from immobilized bacterial cells with 0.05 M NaOH solution.

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Adsorption of antimony and arsenic from a copper electrorefining solution onto activated carbon

Cited by 137 publications

References 8 publications

Metallurgical recovery of metals from electronic waste: A review

Metallurgical recovery of metals from electronic waste: A review

Removal of arsenate from aqueous media by magnetic chitosan resin immobilized with molybdate oxoanions

Investigation on Elimination of As(III) and As(V) from Wastewater Using Bacterial Biofilm Supported on Sawdust/MnFe2O4 Composite

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