Advances and New Variations of the Hirao Reaction

Jablonkai, Erzsébet; Keglevich, György

doi:10.1080/00304948.2014.922376

Cited by 67 publications

(42 citation statements)

References 118 publications

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“…Arylphosphonates, phosphinates or phosphine oxides could all be formed in the coupling reaction of >P(O)H species and aryl halides in the presence of Cu or Ni salts [25]. Starting from the salts of the >P(O)H species, there was no need for any catalysts [26].…”

Section: Microwave-assisted C-p Bond Formationmentioning

confidence: 97%

Microwave-Assisted Syntheses in Organic Chemistry

Kiss

Bálint²,

Keglevich

2016

SpringerBriefs in Molecular Science

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The second part focuses on the summary of typical organic chemical reactions selected, such as coupling reactions (C-C bond formation reactions, carbon-heteroatom bond formations), condensations (aldol-type-, Claisen-, Knoevenagel reaction), multicomponent reactions (Mannich-, Biginelli-, Hantzsch-, Bucherer-Bergs-, Strecker-, Gewald-, Kabachnik-Fields-, Kindler-, Passerini-, Ugi-and domino reactions), cycloadditions (including Diels-Alder reactions). The authors tried to compile fashionable reactions that have been reviewed less in the past years.

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Section: Microwave-assisted C-p Bond Formationmentioning

confidence: 97%

Microwave-Assisted Syntheses in Organic Chemistry

Kiss

Bálint²,

Keglevich

2016

SpringerBriefs in Molecular Science

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“…The P‐C coupling reaction, catalyzed by transition metal complexes, pioneered by Hirao's group, is one of the most effective methods of the synthesis of tertiary achiral and chiral phosphine oxides. Zhang et al employed a dynamic kinetic resolution strategy to obtain a series of enantiomerically enriched tertiary triarylphosphine oxides 27a‐e , using a palladium‐based catalytic system.…”

Section: Cross‐coupling Of Secondary Phosphine Oxides With Aryl Halidmentioning

confidence: 99%

Synthesis of optically active tertiary phosphine oxides: A historical overview and the latest advances

Chrzanowski

Krasowska

Drabowicz

2018

Heteroatom Chemistry

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“…Many variations were elaborated in the last two decades [35,36]. It is noteworthy that the Pd-catalyzed reaction took place efficiently in the presence of Pd(OAc) 2 without any ligand on MW irradiation (Scheme 4) [37].…”

Section: Methodsmentioning

confidence: 99%

Environmentally Friendly Chemistry with Organophosphorus Syntheses in Focus

Keglevich

Grűn²,

Bagi³

et al. 2015

Period. Polytech. Chem. Eng.

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The use of the microwave (MW) Keywords organophosphorus chemistry, green chemistry, microwave, resolution, platinum complexes, dronic acids/dronates IntroductionIn this minireview, our recent results in environmentallyfriendly ("green") chemistry have been summarized. In the first sub-chapter the usefulness of the microwave technique is shown in organophosphorus chemistry. The second sub-chapter summarizes our results on the resolution of cyclic phosphine oxides, as precursors for P-ligands and on the synthesis of platinum complexes as potential catalysts. Catalysts are of utmost importance from the point of view of green chemistry. The last sub-chapter comprises our experiences on the optimization of the synthesis of dronic acid derivatives that are important drugs against bone diseases.

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Advances and New Variations of the Hirao Reaction

Cited by 67 publications

References 118 publications

Microwave-Assisted Syntheses in Organic Chemistry

Microwave-Assisted Syntheses in Organic Chemistry

Synthesis of optically active tertiary phosphine oxides: A historical overview and the latest advances

Environmentally Friendly Chemistry with Organophosphorus Syntheses in Focus

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