Experiments
of coal partial gasification are conducted on a self-designed circulating
fluidized bed (CFB) gasifier. The CFB gasifier system consists of
a furnace, coal-feed system, air-feed system, steam generation system,
gas–solid separation system, temperature- and pressure-measuring
system, and material-returning system. The furnace is surrounded with
electric heating wires, and the height and diameter of the furnace
are 2600 and 120 mm, respectively. The experiments are conducted at
temperatures between 885 and 980 °C. The coal particle size of
0.35–0.9 mm is chosen for experiments. The coal particle is
gasified in the mixture of O2 and steam. The effects of
different oxygen/coal ratios and steam/coal ratios on the performance
of coal partial gasification are studied. As the results show, a higher
oxygen/coal ratio leads to a higher gasification temperature and carbon
conversion, while a slightly higher steam/coal ratio is better for
the quality of syngas. The results show that the volume fraction of
combustible gas and the lower calorific value reach as high as 70%
and 9.1 MJ/Nm3, respectively. It can be obtained from the
results of Raman and Fourier transform infrared spectra that the structure
of chars becomes higher ordered as the different functional groups
are gradually consumed. The chars become less reactive because higher
ordered results in less reactivity.