Aluminate-Based Nanostructured Luminescent Materials: Design of Processing and Functional Properties

Abstract

Interest in luminescent materials has been continuously growing for several decades, looking for the development of new systems with optimized optical properties. Nowadays, research has been focused on the development of materials that satisfy specific market requirements in optoelectronics, radioelectronics, aerospace, bio-sensing, pigment applications, etc. Despite the fact that several efforts have made in the synthesis of organic luminescent materials, their poor stability under light exposure limits their use. Hence, luminescent materials based on inorganic phosphors are considered a mature topic. Within this subject, glass, glass-ceramics and ceramics have had great technological relevance, depending on the final applications. Supposing that luminescent materials are able to withstand high temperatures, have a high strength and, simultaneously, possess high stability, ceramics may be considered promising candidates to demonstrate required performance. In an ongoing effort to find a suitable synthesis method for their processing, some routes to develop nanostructured luminescent materials are addressed in this review paper. Several ceramic families that show luminescence have been intensively studied in the last few decades. Here, we demonstrate the synthesis of particles based on aluminate using the methods of sol-gel or molten salts and the production of thin films using screen printing assisted by a molten salt flux. The goal of this review is to identify potential methods to tailor the micro-nanostructure and to tune both the emission and excitation properties, focusing on emerging strategies that can be easily transferred to an industrial scale. Major challenges, opportunities, and directions of future research are specified.

Phase Formation Specifics in the High-Alumina Region of the СаО–Al2О3 System

“…Of these phases, calcium monoaluminate (CА) and calcium dialuminate (CA 2 ) are of greatest applied importance. Calcium aluminates are used in optical ceramics [5] and construction ceramics [6]. Calcium monoaluminate and calcium dialuminate are the major phases of calcium aluminate (aluminous) cements, which are widely used in the construction, mining, and metallurgical industries [7].…”