2011
DOI: 10.1002/jccs.201190010
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Aluminum(III)‐selective PVC Membrane Electrode Based on Salicylaldehyde Salicyloyl Hydrazone

Abstract: A highly selective PVC membrane electrode for Al 3+ based on salicylaldehyde salicyloyl hydrazone as a neutral carrier has been prepared and studied. The sensor exhibits a good response for Al 3+ over a linear range of 9.0 × 10 -6 to 1.0 × 10 -1 mol/L, with a Nernstian slope of 20.0 ± 0.2 mV/decade and detection limit of 7.0 × 10 -6 mol/L. Selectivity coefficients determined by the method of separate solution indicate high selectivity for Al 3+ . The response mechanism was discussed in view of UV-Vis spectrosc… Show more

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Cited by 9 publications
(3 citation statements)
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“…The performances of the three proposed Al(III) electrodes were compared with the previously reported ones [21,22,28,29,[48][49][50][51][52]. As shown in Table 3, the coated paste electrode showed superior response to the target cation ions over the other proposed sensors because of the wide linear range, short response time and Nernstian slope.…”
Section: Effect Of Response Time Soaking and Life Spanmentioning
confidence: 93%
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“…The performances of the three proposed Al(III) electrodes were compared with the previously reported ones [21,22,28,29,[48][49][50][51][52]. As shown in Table 3, the coated paste electrode showed superior response to the target cation ions over the other proposed sensors because of the wide linear range, short response time and Nernstian slope.…”
Section: Effect Of Response Time Soaking and Life Spanmentioning
confidence: 93%
“…The (dE°/dt) cell values 1.8 × 10 À 5 -1.0 × 10 À 1 2.5-4. 5 10 [22] 19.3 2.5 × 10 À 6 1.0 × 10 À 6 -1.0 × 10 À 1 3.0-8.0 10 [28] 20.0 7.0 × 10 À 6 9.0 × 10 À 6 -1.0 × 10 À 1 2.5-4.0 9 [29] 19.8 4.6 × 10 À 7 1.0 × 10 6 -1.0 × 10 À 1 2.0-6.0 8 [48] 19.4 1.0 × 10 À 6 2.0 × 10 À 6 -2.0 × 10 À 2 3.5-5.0 5 [49] 19.2 1.6 × 10 À 7 4.5 × 10 À 7 -1.6 × 10 À 3 2.2-4.0 15 [50] 15.6 5.1 × 10 À 6 1.0 × 10 À 5 -1.5 × 10 À 2 3.5-4.5 < 10 [51] 19.0 5.5 × 10 À 7 1.0 × 10 À 6 -1.0 × 10 À 1 4.0-8.0 15 [52] 19.6 1.0 × 10 À 5 2.04 × 10 À 5 -1.99 × 10 À 1 2.0-4.0 5.0 This Work MCP 20.0 1.00 × 10 À 6 1.00 × 10 À 6 -1.00 × 10 À 2 4.5-6.5 10 PVC…”
Section: Effect Of Temperatureunclassified
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