2022
DOI: 10.1016/j.cattod.2020.06.031
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Amine-functionalized titanium dioxide supported dioxidomolybdenum(VI) complexes as functional model for phenoxazinone synthase enzyme

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Cited by 7 publications
(8 citation statements)
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“…Mesoporous supported [Cu(hap‐aptms)]@MCM‐41 (Hhap‐aptms=Schiff base of o ‐hydroxyacetophenone and 3‐aminopropyltrimethoxysilane) gave even further poor result of 42 % conversion of OAP in 3 h utilizing oxidant t ‐BuOOH in MeOH solvent at a temperature of 70 °C [17] . Two structurally closed catalysts [Mo VI O 2 {Hdfba(bhz) 2 }(H 2 O)]@APTMS‐TiO 2 and [Mo VI O 2 {Hdfba(fah) 2 }(H 2 O)]@APTMS‐TiO 2 (H 4 dfba(bhz) 2 /H 4 dfba(fah) 2 =Schiff base derived from 3,5‐diformyl‐4‐hydroxybenzoic acid and benzoylhydrazide/2‐furanoylhydrazide) under almost similar conditions as reported for 3 and 4 gave almost similar yield of 94 and 88 % in 6 h, respectively [42] . Sarkar et al .…”
Section: Resultssupporting
confidence: 60%
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“…Mesoporous supported [Cu(hap‐aptms)]@MCM‐41 (Hhap‐aptms=Schiff base of o ‐hydroxyacetophenone and 3‐aminopropyltrimethoxysilane) gave even further poor result of 42 % conversion of OAP in 3 h utilizing oxidant t ‐BuOOH in MeOH solvent at a temperature of 70 °C [17] . Two structurally closed catalysts [Mo VI O 2 {Hdfba(bhz) 2 }(H 2 O)]@APTMS‐TiO 2 and [Mo VI O 2 {Hdfba(fah) 2 }(H 2 O)]@APTMS‐TiO 2 (H 4 dfba(bhz) 2 /H 4 dfba(fah) 2 =Schiff base derived from 3,5‐diformyl‐4‐hydroxybenzoic acid and benzoylhydrazide/2‐furanoylhydrazide) under almost similar conditions as reported for 3 and 4 gave almost similar yield of 94 and 88 % in 6 h, respectively [42] . Sarkar et al .…”
Section: Resultssupporting
confidence: 60%
“…[17] Two structurally closed catalysts [Mo VI O 2 {Hdfba(bhz) 2 }(H 2 O)]@APTMS-TiO 2 and [Mo VI O 2 {Hdfba(fah) 2 }(H 2 O)]@APTMS-TiO 2 (H 4 dfba(bhz) 2 / H 4 dfba(fah) 2 = Schiff base derived from 3,5-diformyl-4-hydroxybenzoic acid and benzoylhydrazide/2-furanoylhydrazide) under almost similar conditions as reported for 3 and 4 gave almost similar yield of 94 and 88 % in 6 h, respectively. [42] [Mn II (L 1 )Cl]Cl [d] [Mn II (L 2 )Cl]Cl MeOH 440 234 [13] 5.…”
Section: Catalytic Comparison With Literature Datamentioning
confidence: 99%
“…The ligand I can easily be immobilized onto amine-functionalized titania in DMF to obtain [H 2 hptb]@APTMS-TiO 2 ( II ). 26 Complex 1 was characterized successfully by various spectroscopic (FT-IR, UV-visible, 1 H and 13 C NMR) techniques, elemental and thermal studies. Titania supported ligand II , and complex 2 were additionally characterized by MP-AES, DRS, P-XRD, XPS and TEM.…”
Section: Resultsmentioning
confidence: 99%
“…All materials and solvents were utilized as acquired. TiO 2 , 46 amine-functionalized titanium dioxide (APTMS-TiO 2 ), 47 [W VI O 2 (acac) 2 ], 48,49 H 3 hptb ( I ) 50 and [H 2 hptb]@APTMS-TiO 2 ( II ) 26 were prepared according to the earlier reported method. Before use, toluene was dried over sodium and distilled.…”
Section: Methodsmentioning
confidence: 99%
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