1985
DOI: 10.1002/cber.19851180326
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Aminyloxide (Nitroxide), XXXVII. Bildung und ESR‐spektroskopische Untersuchung von Vinylaminyloxiden mit Elektronenacceptor‐Substituenten und von verwandten Radikalen

Abstract: Vinylaminyloxide mit Elektronenacceptor-Substituenten in 0-Stellung wurden nach verschiedenen Methoden hergestellt. Oxidation von Nitronen 6 oder den tautomeren N-Vinylhydroxylaminen 7 ergibt die Radikale 8a, b, z und ae. 8oe und ue entstehen bei der Oxidation der Isoxazoline, die in situ aus den Isoxazoliumsalzen 12 erzeugt werden. Die Bisvinylaminyloxide 16 und 17 werden bei der Oxidation der entsprechenden N,N-Bisvinylhydroxylamine erhalten. Die Oxidation Formation of Vinylaminyl Oxides Substituted by Elec… Show more

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Cited by 36 publications
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“…The addition proceeds regiospecifically. The most commonly utilized activating groups are ester 101 , carboxyl 102 , sulfone 103 , ketone 104 and 2-pyridyl 105 . Depending on reaction conditions, addition of hydroxylamines to α,β-unsaturated ketones can be accompanied by formation of oximes 106,107 .…”
Section: E Nucleophilic Addition Of Hydroxylamines To Activated C=c mentioning
confidence: 99%
“…The addition proceeds regiospecifically. The most commonly utilized activating groups are ester 101 , carboxyl 102 , sulfone 103 , ketone 104 and 2-pyridyl 105 . Depending on reaction conditions, addition of hydroxylamines to α,β-unsaturated ketones can be accompanied by formation of oximes 106,107 .…”
Section: E Nucleophilic Addition Of Hydroxylamines To Activated C=c mentioning
confidence: 99%