2000
DOI: 10.1016/s0014-3057(99)00116-0
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Ammonia sensitivity of polyaniline films via emulsion polymerization

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Cited by 48 publications
(32 citation statements)
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“…In this work, the NH 3 sensitivity of PANi layer made by in situ chemical polymerisation is comparable to that of PANi layer made by emulsion polymerisation [12] and relatively lower than that of casting fibrillar PANi layer [14]. However, its sensitivity is found to be higher than that of casting electrochemically polymerised PANi layer [15].…”
Section: Resultsmentioning
confidence: 68%
See 1 more Smart Citation
“…In this work, the NH 3 sensitivity of PANi layer made by in situ chemical polymerisation is comparable to that of PANi layer made by emulsion polymerisation [12] and relatively lower than that of casting fibrillar PANi layer [14]. However, its sensitivity is found to be higher than that of casting electrochemically polymerised PANi layer [15].…”
Section: Resultsmentioning
confidence: 68%
“…Then, a molar equivalent aqueous solution of 0.12 M APS was gradually dropped into the PANi solution [11,12]. The solution colour was gradually changed to dark blue-green indicating that the PANi was formed in the solution.…”
Section: Methodsmentioning
confidence: 99%
“…Protonation of the emeraldine base or the oxidation of leucoemeraldine base can lead to the formation of a semiconductor or conductor. Interaction with NH 3 should deprotonate the emeraldine salt into base forming NH 4 + thereby decreasing the conductivity [24]. Both decrease as well as increase in current has been observed for PANI films on interaction with NO 2 [11,23].…”
Section: No 2 and Nh 3 Gas Sensing Mechanismmentioning
confidence: 93%
“…To improve the gas-sensing properties, an effective method is hybridization, which can synergize or complement the sensitive properties of pure organic or inorganic gas-sensing material [15,16]. Among those composite materials, PANI-based composite gained special interest due to its good environmental and chemical stability, ease of synthesis, inexpensive monomer as well as higher sensitivity, reversible response and shorter response time [17]. Up to now, many sensitive gas sensors based on PANI nanocomposites combined with various metal oxides (SnO 2 [15], TiO 2 [18,19], MoO 3 [20], WO 3 [21], and In 2 O 3 [16]) have been reported.…”
Section: Introductionmentioning
confidence: 99%