This paper describes a new zeta potential altering system (ZPAS) that is based on an inner salt developed between an organic polymer (OP) and an ester for fines, sand and proppant flowback control. The objective of this work was to develop a ZPAS with an enhanced environmental profile and better product performance as it relates to intensity of particle agglomeration and thermal stability under wide range of downhole operating conditions.
The effect of molecular weight of the organic polymer after blending with different esters on zeta potential, rheology, agglomeration, fines production, sand production, regain permeability, fracture conductivity, flash point and EC50 concentration was investigated and compared to the performance of the existing ZPAS. Zeta potential was measured using a Zetasizer Nano Z System manufactured by Malvern, rheology with Anton Paar and ARES G2, sand production with a Maximum Sand Free Rate (MSFR) Test, regain permeability with a Chandler Engineering Formation Response Tester, fracture conductivity, indentation force with a Texture Analyzer, flash point with Miniflash FLP/FLPH/FLPL and EC50 concentration with a Modern Water Microtox Model 500 Analyzer.
When the organic polymer was blended with an ester, the odor was minimized substantially and toxicity reduced 400 times as compared to the current ZPAS. This organic polymer has a considerably higher molecular weight than the prior oligomeric ZPAS system. 1 This molecular weight enhancement improves the degree of agglomeration as measured by indentation testing and provides better thermal stability. Force in grams as measured with the indentation tester increased as the organic polymer concentration and molecular weight was increased in the new ZPAS formulation. The force in grams is an indicator of the effectiveness of sand consolidation. There was no sand produced at 180° F with 20/40 mesh sand and a confining pressure of 400 psi in the MSFR test. Regain permeability of 60 to 82% was obtained in low permeability sandstone. High MW ZPAS was more effective than medium MW ZPAS at 2,000 psi closure stress while medium MW ZPAS was more effective at 6,000 psi closure stress. The oscillatory rheometer indicated that the polymeric ZPAS is a Newtonian fluid which makes it easy to pump. After sand is agglomerated with the ZPAS, the agglomerated sand becomes viscoelastic. The elasticity is maintained to a temperature of at least 180°F. The stronger sand consolidation and more deformable agglomerate provided by this new generation ZPAS as compared to the current ZPAS is useful in producing more oil without incremental sand production.