Recently, a new type of LNG tank named "KC-1 membrane LNG tank" has been developed by Korean Gas Corporation (KOGAS), and Samsung Heavy Industries (SHI) is currently building KC-1 membrane type LNG carriers. Unlike other LNG tanks, the KC-1 membrane LNG tank has a single-insulation structure rather than a double-insulation structure. For a given tank's boundary condition, heat transfer analysis is performed from the external to the internal environment of the LNG tank by numerical simulation for three tanks. In each tank, the main thermally resistant layer of insulation is assembled with a High density rigid Polyurethane Foam (H-PUF), which is blown with one of three different types of hydrofluorocarbons-namely-HFC-365mfc, 245fa, and 245fa-e (enhanced). Advantage of such blowing agents is that it has a lower Ozone Depletion Potential (ODP) than HCFC-141b or carbon dioxide ( ) that has been used in the past as well as having low thermal conductivity. A Reduced Order Model is utilized to a 3-dimensional section of the insulation to calculate equivalent thermal conductivity. The equivalent thermal conductivity of the insulation is then applied to the rest of LNG tank, reducing the size of tank simulation domain as well as computation time. Tank's two external and internal boundary conditions used are those defined by the International Code for the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk (IGC) and the United States Coast Guard (USCG) conditions. Boil-off Rate (BOR) of the tank that has the insulation with H-PUF blown with respectively..