Based on two types of priority queues, this paper proposes a polling scheduling strategy with reserved channel (Ps-rc strategy) for predefined priority services in cognitive radio networks (CRNs). Channel assembling (CA) technology and spectrum adaptation (SA) technology are adopted to dynamically adjust the assembled channels of secondary users (SUs) to improve the performance of the secondary network. Specifically, the SUs in CRNs are divided into two queues with different priorities; based on polling scheduling, a part of the idle channel is reserved for high-priority queue during the polling stage of the low-priority queue. The purpose is to increase the service quality (QoS) of high priority on the basis of providing fair scheduling. Furthermore, the CA-based channel access process of the proposed strategy is presented and modeled by continuous time Markov chain (CTMC). Then, the process of resource flow between users is mapped on CTMC, and the transition conditions and parameter sets of channel assembling covering all user activities of the system are derived. Finally, the system performance of the proposed CA-based Ps-rc scheduling strategy is simulated and evaluated, including network capacity, spectrum utilization, blocking probability, and forced termination probability. Numerical results show that the proposed strategy can improve the QoS of the predefined high-priority service without causing excessive starvation problem of low-priority service.