An Efficient Synthesis of Symmetrical<i>N</i>,<i>N’</i>-Alkylidene Bisamides Catalyzed by Silica Supported Perchloric Acid

We contributed a new benzimidate chemistry through moisture-insensitive NiII/NiII-FeIII combo-catalysis for a simultaneous 2–3 bond-forming gem-diamidation and amidoindolyzation cascade reaction to construct symmetrical and unsymmetrical gem-(arylmethylene)amides and indolo(arylmethylene)amides, using emerging benzimidate synthons. The operational simplicity, mild nature, generality, and robustness of the strategy were validated through syntheses of a wide range of new molecules, labile sugar-based chiral compounds, and pharmaceuticals with high yields under the same reaction conditions.

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Synthesis of symmetrical N,N′-alkylidene bis-amides catalyzed by silica coated magnetic NiFe₂O₄ nanoparticle supported polyphosphoric acid (NiFe₂O₄@SiO₂-PPA) and its application toward silver nanoparticle synthesis for electrochemical detection of glucose

Maleki

Baghayeri

2015

RSC Adv.

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An Efficient Synthesis of SymmetricalN,N’-Alkylidene Bisamides Catalyzed by Silica Supported Perchloric Acid

Cited by 4 publications

References 2 publications

Montmorillonite K10: An efficient organo heterogeneous catalyst for one-pot synthesis of new N,N′-alkylidene bisamide derivatives under solvent free condition

Montmorillonite K10: An efficient organo heterogeneous catalyst for one-pot synthesis of new N,N′-alkylidene bisamide derivatives under solvent free condition

Benzimidates as gem-Diamidation and Amidoindolyzation Cascade Synthons with a Hydrated Ni^II Catalyst

Synthesis of symmetrical N,N′-alkylidene bis-amides catalyzed by silica coated magnetic NiFe₂O₄ nanoparticle supported polyphosphoric acid (NiFe₂O₄@SiO₂-PPA) and its application toward silver nanoparticle synthesis for electrochemical detection of glucose

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An Efficient Synthesis of SymmetricalN,N’-Alkylidene Bisamides Catalyzed by Silica Supported Perchloric Acid

Cited by 4 publications

References 2 publications

Montmorillonite K10: An efficient organo heterogeneous catalyst for one-pot synthesis of new N,N′-alkylidene bisamide derivatives under solvent free condition

Montmorillonite K10: An efficient organo heterogeneous catalyst for one-pot synthesis of new N,N′-alkylidene bisamide derivatives under solvent free condition

Benzimidates as gem-Diamidation and Amidoindolyzation Cascade Synthons with a Hydrated NiII Catalyst

Synthesis of symmetrical N,N′-alkylidene bis-amides catalyzed by silica coated magnetic NiFe2O4 nanoparticle supported polyphosphoric acid (NiFe2O4@SiO2-PPA) and its application toward silver nanoparticle synthesis for electrochemical detection of glucose

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About

Benzimidates as gem-Diamidation and Amidoindolyzation Cascade Synthons with a Hydrated Ni^II Catalyst

Synthesis of symmetrical N,N′-alkylidene bis-amides catalyzed by silica coated magnetic NiFe₂O₄ nanoparticle supported polyphosphoric acid (NiFe₂O₄@SiO₂-PPA) and its application toward silver nanoparticle synthesis for electrochemical detection of glucose