An experimental investigation of molecular interactions between [Emim][triflate] ionic liquid & 2-alkoxyethanols and theoretical comparison by PFP theory

Volumetric, Ultrasonic, Spectroscopic, and Molecular Dynamics Simulations Studies of Molecular Interactions in Binary Mixtures of [Emim][NTf2] with 2-Propoxyethanol at Temperatures from 298.15 to 318.15 K

“…The density and speed of sound values of pure 2-PE have been taken from our previous work. 43 All the samples were dried out for a period around 72 h under a vacuum (0.1 Pa) and temperature range of 100−120 °C, and the water content is found to be less than 150 ppm, which is much lower than the original pre-evacuation analysis, which showed values around 210 ppm. 2.2.…”

“…Combined uncertainties (confidence level, 95%): U c ( V m ) = 0.05 × 10 –6 m 3 mol –1 , U c ( κ s ) = 0.01 × 10 –10 Pa –1 , U c ( α p ) = 0.01 × 10 –4 K –1 . All the experiments were carried out at atmospheric pressure. b Aangothu et al …”

“…The purities are verified by comparing the measured density, speed of sound, and refractive index of the pure liquids with the literature at various temperatures and ambient pressure and are given in Table . The density and speed of sound values of pure 2-PE have been taken from our previous work . All the samples were dried out for a period around 72 h under a vacuum (0.1 Pa) and temperature range of 100–120 °C, and the water content is found to be less than 150 ppm, which is much lower than the original pre-evacuation analysis, which showed values around 210 ppm.…”

“… a Standard uncertainties u are u (ρ) = 0.15 kg m –3 , u ( u ) = 1.5 m s –1 , u ( T ) = 0.01 K, and u ( P ) = 1.0 kPa. b Yao et al c Anwar et al d Bansal et al e Gonzalez et al f Srilakshmi et al g Reddy et al h Krishna et al I Reddy et al j Gonzalez et al k Aangothu et al …”

Novel Binary Mixtures of Alkanolamine Based Deep Eutectic Solvents with Water—Thermodynamic Calculation and Correlation of Crucial Physicochemical Properties

“…Over time, however, it has emerged that the use of the Flory formalism can still provide an interesting correlation between the excess volumes of more complex mixtures. So far, the PFP theory has been successfully applied to predict and model the excess molar volumes of many mixtures containing ionic liquids [ 46 , 47 , 48 , 49 , 50 ] and some aqueous systems with deep eutectic solvents [ 18 , 51 , 52 ].…”