2007
DOI: 10.1088/0022-3727/40/14/029
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An experimental study of the charging regime of the composite (PANI5%/PMMA)

Abstract: The charge dynamics of insulating or weakly conductive materials can be studied by the secondary electronic emission (SEE) method. Those two types of compounds behave differently to irradiation: charge trappers such as PMMA or SiO2 can have a charge excess after irradiation, so that they can be trapped for a long time, and can even cause ‘microbreakdowns’ to dielectric breakdowns, while in contrast, conductive materials have a kind of charge flow. SEE yield can also be affected by changing the current density.… Show more

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Cited by 4 publications
(4 citation statements)
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“…34 Moreover, electron-charging effects were encountered throughout the entire cross-sections shown in Figure 3b and c, which was ascribed to the abundant C-dots-an organic substance-within the PSiO 2 pores. 35,36 The TEM and HRTEM images shown in Figure 3d and e, respectively, reveal the structural features of the C-dots prepared in situ within the nanoscale pores. The C-dots extracted from the PSiO 2 matrix by dissolving the porous host in hydrofluoric acid appear uniform (see Figure 3d; the size distribution analysis indicates a value of 3.7 ± 0.6 nm, Supplementary Figure S2, Supporting Information).…”
Section: Resultsmentioning
confidence: 96%
“…34 Moreover, electron-charging effects were encountered throughout the entire cross-sections shown in Figure 3b and c, which was ascribed to the abundant C-dots-an organic substance-within the PSiO 2 pores. 35,36 The TEM and HRTEM images shown in Figure 3d and e, respectively, reveal the structural features of the C-dots prepared in situ within the nanoscale pores. The C-dots extracted from the PSiO 2 matrix by dissolving the porous host in hydrofluoric acid appear uniform (see Figure 3d; the size distribution analysis indicates a value of 3.7 ± 0.6 nm, Supplementary Figure S2, Supporting Information).…”
Section: Resultsmentioning
confidence: 96%
“…Polímeros orgânicos como o poli(3,4-etileno dioxitiofeno):poli(estireno sulfonato) (PEDOT:PSS) e a polianilina (PAni) tem sido utilizados como camadas transportadoras de cargas em dispositivos optoeletrônicos orgânicos por serem condutores elétricos e pela facilidade de processamento [3][4][5] . Em solução aquosa, a PAni pode ser depositada em substratos através 88 Polímeros, vol.…”
Section: Introductionunclassified
“…Os materiais semicondutores orgânicos, como os polímeros, são candidatos potencialmente promissores para aplicações no campo de dispositivos fotovoltaicos, em particular, as células solares por apresentarem extensos intervalos de absorção luminosa, podem ser fabricadas tanto em substratos rígidos quanto em substratos flexíveis e a custo competitivo e inferior aos tradicionais fotovoltaicos à base de materiais inorgânicos (Si) [1,2] . Entretanto, a eficiência de conversão de radiação em energia pelas células solares orgânicas é limitada pela baixa taxa de dissociação dos éxcitons em cargas livres e pelo pobre transporte de cargas foto-geradas até o eletrodo coletor devido, em partes, às altas taxas de recombinação e à baixa mobilidade dos portadores de cargas.Polímeros orgânicos como o poli(3,4-etileno dioxitiofeno):poli(estireno sulfonato) (PEDOT:PSS) e a polianilina (PAni) tem sido utilizados como camadas transportadoras de cargas em dispositivos optoeletrônicos orgânicos por serem condutores elétricos e pela facilidade de processamento [3][4][5] . Em solução aquosa, a PAni pode ser depositada em substratos através 88 Polímeros, vol.…”
unclassified
“…These conducting polymers are deposited from an aqueous dispersion by spin-coating method. Polyaniline (PANI) is another promising HTL for these kind of applications [10,11]. In doped form, PANI (emeraldine salt) is intrinsically conductive (4.4 Ω − 1 cm − 1 ) [12].…”
Section: Introductionmentioning
confidence: 99%