An Extended Ag^I Cluster‐Based Framework Solid: Silver‐Thiolate Cluster Linked Polyoxometalate Including Ag^I···H–C Anagostic Interactions

Abstract

In this contribution, a new crystalline silver(I) clusterbased coordination polymer, {[Ag 11 (iBuS) 9 (CH 3 CN)](Mo 6 O 19 )} n (SD/Ag11a) has been prepared and structurally characterized by single-crystal X-ray diffraction. The structure of SD/Ag11a consists of an asymmetric unit of Ag 11 S 9 cluster, in which the coordination number of the eleven silver atoms varies from two to four and the Ag···Ag contacts in the cluster range from 2.897 to 3.374 Å. Each Ag 11 S 9 cluster is interconnected by thiolate ligands iBuS -, thus forming one-dimensional (1-D) coordination [a]

Trapping of Ag+ into a Perfect Six-Coordinated Environment: Structural Analysis, Quantum Chemical Calculations and Electrochemistry

“…Ag + /L/polyoxometalate hybrid organic–inorganic systems are attractive candidates for engineering multifunctional coordination networks. In this field, numerous works have been contributed by Cronin [ 1 , 2 , 3 , 4 , 5 ], Wang [ 6 , 7 ], Sun [ 8 , 9 , 10 ], Mac [ 11 ], and Niu et al [ 12 , 13 ]. The versatility of Ag-based supramolecular building blocks opens almost limitless opportunities to create coordination networks of different topologies and compositions [ 14 , 15 , 16 , 17 , 18 , 19 , 20 , 21 , 22 ].…”

Array configurations of oxometallate–Ag cluster hybrid nanocomposites

“…16c). 60 Zang’ group introduced [Mo 6 O 19 ] 2− into Ag–S systems to synthesize another coordination polymer [Ag 10 (S t Bu) 6 (CH 3 CN) 8 (Mo 6 O 19 ) 2 ] n (Fig. 16d), 61 which exhibits green photoluminescence at room temperature.…”

Assembly of Copper Alkynyl Clusters into Dimensionally Diverse Coordinated Polymers Mediated by Pyridine Ligands

“…However, even inert metal clusters, such as gold and silver clusters, may exhibit air sensitivity, thus underscoring the urgent need to enhance their stability. , Notably, the assembly of clusters into atomically precise cluster-based polymers not only augments material stability but also amalgamates the inherent advantages of both clusters and polymers. These advantages were reflected in the construction of highly interconnected frameworks with numerous nuclear cluster nodes, enhanced structural tunability, increased structural complexity, widened channels, and improved robustness. − Such prospective benefits render these materials highly appealing for a diverse array of applications, spanning sensing, catalysis, and gas separation. In recent investigations, silver sulfide clusters, such as Ag 10 , Ag 12 , and Ag 14 , have been demonstrated to assemble into one-, two-, and three-dimensional frameworks, wherein the nanoclusters serve as nodes interconnected by pyridine-type organic linkers. − Notably, contrasted to the high stability in gold and silver clusters, copper­(I) clusters exhibit higher susceptibility to oxidation, which has posed a significant challenge in the preparation of stable copper­(I) clusters and hinders property research. , …”