Search citation statements
Paper Sections
Citation Types
Year Published
Publication Types
Relationship
Authors
Journals
<p><strong>Introduction</strong></p> <p>With the confirmation of water ice in the lunar polar regions [1], the Moon has recently come into the focus of attention of international space agencies again. Volatiles, specifically water and hydrogen, are important resources both for life support and for potential applications as fuels and propellants for spacecraft. In-situ resource utilization (ISRU) of volatiles could significantly reduce the costs of a sustained presence on the Moon and could be beneficial for the future human deep space exploration of the solar system [2]. The detection of volatiles is therefore an important scientific goal for future robotic missions to the Moon.</p> <p>The LUVMI-X project (Lunar Volatiles Mobile Instrumentation &#8211; Extended) is developing an initial system design as well as payload and mobility breadboards for the detection of volatiles in the lunar polar region on a small, lightweight rover [3]. The LUVMI-X rover is shown in Figure 1. One proposed scientific payload is VOILA (Volatiles Identification by Laser Ablation), which is jointly developed by OHB System AG (OHB), Laser Zentrum Hannover (LZH), and the German Aerospace Center&#8217;s Institute of Optical Sensor Systems (DLR-OS). VOILA will use laser-induced breakdown spectroscopy (LIBS) to analyze the elemental composition of the lunar surface, with a special focus on detecting and quantifying hydrogen and oxygen as indicators for water.</p> <p>LIBS is a versatile technique that requires only optical access to its target [4]. A LIBS spectrum is obtained within seconds, making it well-suited for quick analyses of multiple targets in proximity to the rover. LIBS was first used in space by the ChemCam instrument on board NASA&#8217;s Curiosity rover on Mars [5, 6]. The first LIBS instrument on the Moon was supposed to operate on board the Pragyan rover of India&#8217;s Chandrayaan-2 mission [7]. However, the Chandrayaan-2 lander failed a soft landing in September 2019.</p> <p>Here, we present a summary of the VOILA instrument design and its intended capabilities for volatiles detection at the lunar south pole.</p> <p><img src="data:image/png;base64, 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
<p><strong>Introduction</strong></p> <p>With the confirmation of water ice in the lunar polar regions [1], the Moon has recently come into the focus of attention of international space agencies again. Volatiles, specifically water and hydrogen, are important resources both for life support and for potential applications as fuels and propellants for spacecraft. In-situ resource utilization (ISRU) of volatiles could significantly reduce the costs of a sustained presence on the Moon and could be beneficial for the future human deep space exploration of the solar system [2]. The detection of volatiles is therefore an important scientific goal for future robotic missions to the Moon.</p> <p>The LUVMI-X project (Lunar Volatiles Mobile Instrumentation &#8211; Extended) is developing an initial system design as well as payload and mobility breadboards for the detection of volatiles in the lunar polar region on a small, lightweight rover [3]. The LUVMI-X rover is shown in Figure 1. One proposed scientific payload is VOILA (Volatiles Identification by Laser Ablation), which is jointly developed by OHB System AG (OHB), Laser Zentrum Hannover (LZH), and the German Aerospace Center&#8217;s Institute of Optical Sensor Systems (DLR-OS). VOILA will use laser-induced breakdown spectroscopy (LIBS) to analyze the elemental composition of the lunar surface, with a special focus on detecting and quantifying hydrogen and oxygen as indicators for water.</p> <p>LIBS is a versatile technique that requires only optical access to its target [4]. A LIBS spectrum is obtained within seconds, making it well-suited for quick analyses of multiple targets in proximity to the rover. LIBS was first used in space by the ChemCam instrument on board NASA&#8217;s Curiosity rover on Mars [5, 6]. The first LIBS instrument on the Moon was supposed to operate on board the Pragyan rover of India&#8217;s Chandrayaan-2 mission [7]. However, the Chandrayaan-2 lander failed a soft landing in September 2019.</p> <p>Here, we present a summary of the VOILA instrument design and its intended capabilities for volatiles detection at the lunar south pole.</p> <p><img src="data:image/png;base64, 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
The first detection of gypsum (CaSO4·2H2O) by the Mars Science Laboratory (MSL) rover Curiosity in the Gale Crater, Mars created a profound impact on planetary science and exploration. The unique capability of plasma spectroscopy, which involves in situ elemental analysis in extraterrestrial environments, suggests the presence of water in the red planet based on phase characterization and provides a clue to Martian paleoclimate. The key to gypsum as an ideal paleoclimate proxy lies in its textural variants and terrestrial gypsum samples from varied locations and textural types have been analyzed with laser-induced breakdown spectroscopy (LIBS) in this study. Petrographic, sub-microscopic, and powder X-ray diffraction characterizations confirm the presence of gypsum (hydrated calcium sulphate; CaSO4·2H2O), bassanite (semi-hydrated calcium sulphate; CaSO4·½H2O), and anhydrite (anhydrous calcium sulphate; CaSO4), along with accessory phases (quartz and jarosite). The principal component analysis of LIBS spectra from texturally varied gypsums can be differentiated from one another due to the chemical variability in their elemental concentrations. The concentration of gypsum is determined from the partial least-square regressions model. The rapid characterization of gypsum samples with LIBS is expected to work well in extraterrestrial environments.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2025 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.