We measured the electronic properties and gas sensing response of nanowires containing segments of poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT/PSS) that were synthesized using anodic aluminum oxide (AAO) membranes. The nanowires have a "striped" structure of gold-PEDOT/PSS-gold and are typically 8 μm long (1 μm-6 μm-1 μm for each section, respectively) and 220 nm in diameter. Dielectrophoretic assembly was used to position single nanowires on pre-fabricated gold electrodes. A polymer conductivity of 11.5 0.7 S/cm and a contact resistance of 27.6 4 k were inferred from resistance measurements of nanowires of varying length and diameter. When used as gas sensors, the wires showed a resistance change of 10.5%, 9%, and 4% at the saturation vapor pressure of acetone, methanol and ethanol, respectively. Sensor response and recovery were rapid (seconds) with excellent reproducibility in time and across devices. "Striped" template-grown nanowires are thus intriguing candidates for use in electronic nose vapor sensing systems.Keywords: polymer nanowire vapor sensor dielectrophoretic assembly
Biography of authorsYaping Dan received his bachelor and master degrees in microelectronics from Xi'an Jiaotong University in 1999 and Tsinghua University in 2002. He is currently a PhD student in the department of Electrical and Systems Engineering at the University of Pennsylvania. His research interests include nanoscale gas sensors, dielectrophoretic assembly, nanowire synthesis and nanofabrication. Yanyan Cao received her bachelor's degree in Applied Chemistry and her M.S. degree in Supramolecular Chemistry from Tongji University. She is now a graduate student in Thomas E. Mallouk's group at Penn State, where she is working on the design, synthesis and application of functional materials especially for chemical sensing. Thomas E. Mallouk was a graduate student at the University of California, Berkeley, and a postdoctoral fellow at MIT. In 1985, he joined the Chemistry faculty at the University of Texas at Austin. In 1993 he moved to Penn State, where he is now DuPont Professor of Materials Chemistry and Physics. His research has focused on the application of inorganic materials to different problems in solid state and surface chemistry, including photochemical energy conversion, nanoscale electronics, catalysis and electrocatalysis, chemical sensing, superconductivity, and environmental remediation. A.T. Charlie Johnson was a graduate student at Harvard University and a postdoctoral fellow at the Delft University of Technology and the National Institute of Standards and Technology (Boulder). He has been at the University of Pennsylvania since 1994 and is now an Associate Professor in the Department of Physics and Astronomy, with secondary appointments in Electrical and Systems 17 Engineering, and Materials Science and Engineering. His current research interests include gas sensing using carbon nanotubes functionalized with biomolecules and polymer nanowires, single molecule electronics, and the synthesis of...