An investigation of aspects of mine waste from a kyanite mine, Central Virginia, USA

Abstract

Kyanite Mining Corporation, located in Dillwyn, Virginia has been in operation for over 50 years and their local operation is the largest kyanite mine in the world. As part of the processing at this location, a magnetic separate is generated and a minimum estimation of 3.57 million tons of waste has accumulated. Currently no use for the magnetic separate has been identified. We investigated eight representative samples of the magnetic mine waste which varied in color from a dark tan to black, to determine if the waste could be recycled as an ore or could be used as an environmental media. Mineralogical investigations indicate the composition of the magnetic mine waste is dominated by magnetite, kyanite, lesser amounts of hematite and charcoal. Magnetite occurs as fine grained crystals and as inclusions in kyanite. Hematite occurs largely as botryoidal textures, as discrete grains, and as coatings on kyanite grains. Fe-oxide spheres ranging in diameter from approximately 5-100 lm are common and may compose up to 10% in some samples. Titanium dioxide was rarely observed as coatings on silicate mineral grains. Energy dispersive spectroscopy analysis on magnetite crystals indicates they have end-member compositions. Bulk property investigations indicate that grain size distributions of samples are primarily unimodal with 20-40% of material being between 0.600 and 0.250 mm.Hydraulic conductivity values of samples investigated vary between 0.0036 and 0.0077 cm/s and are broadly consistent with those expected of sands with similar grain size distributions. In addition to the magnetic waste stream a light blue, water soluble, amorphous Cu sulfate occurs as a coating on surfaces of boulders. The coating is composed of rounded interlocking particles 5-60 lm in diameter. This material is of some environmental concern for freshwater invertebrates, but can be managed using sorption media. Hyperspectral data were gathered of the magnetic separate, kyanite ore samples, and the light blue Cu sulfate. The signatures of the kyanite ore, the blue mineral coating, and a mixture of the two provide spectral fingerprints that an imaging spectrometer could exploit for rapid detection and subsequent environmental monitoring.

A Reflective Spectroscopy and Mineralogical Investigation of Cosmetic Blush (Wet‘N’Wild) Potentially for Forensic Investigations Related to Interpersonal Violence—An Experimental Feasibility Study

“…The instrument is equipped with a Bruker Quantax 200 STEM EDXS system. The TEM methods detailed above have been used in several previous investigations [20][21][22][23][24][25][26].…”

“…The values for low noise equivalent delta radiance (NeDL) are 1.1 × 10 −9 W/cm 2 /sr/nm at 700 nm for UV/VNIR, 2.8 × 10 −9 W/cm 2 /sr/nm at 1400 nm for NIR, and 5.6 × 10 −8 W/cm 2 /sr/nm at 2100 nm. Several previous versions of the ASD (PANalytical) FieldSpec 4 Hi-Res have been produced, and prior work has utilized this technology in a range of settings and contexts [20,[29][30][31][32][33].…”

Mineralogical and geochemical investigations of silicate-rich mine waste from a kyanite mine in central Virginia: implications for mine waste recycling

“…Cu has been recognized to occur as a poorly crystalline Cu sulfate in some regions of the mine (Krekeler et al 2009). A specific Cu phase was not identified in the waste stream samples.…”

“…The Willis Mountain kyanite ore deposits were once thought to be produced from simple prograde metamorphism of aluminum-rich sandstones; however, further studies have interpreted the protolith as being igneous rocks altered by high-sulfur hydrothermal activity (Owens and Pasek 2007). Further geologic details of the region can be found in Krekeler et al (2009) and references therein. Of the kyanite quartzite, 20-30% is industrial mineral grade kyanite.…”

“…A pyriterich waste stream is separated into sealed silos or more commonly is sold. A second waste stream of magnetic separate dominated by magnetite and pyrrhotite accumulates in a stock pile and an estimated 3.57 million metric tons of this material has accumulated since the late 1940s (Krekeler et al 2009). The largest waste stream is silicaterich material that is dominantly quartz and muscovite.…”