The present study examines the seasonal relationship between land surface temperature (LST) and normalized difference water index (NDWI) on various land surfaces in Raipur City of India by using a series of Landsat images for four specific seasons since 1991-92. The LST is retrieved using the mono-window algorithm technique. The results show that the LST of the study area is noticeably affected by surface composition. The best correlation (correlation coefficient r = 0.42) between the LST and NDWI is achieved in the post-monsoon season, followed by the monsoon season (r = 0.33), pre-monsoon season (r = 0.25), and winter season (r = 0.04). There is a moderate negative correlation (r =-0.49,-0.33,-0.31, and-0.25 in the premonsoon, monsoon, post-monsoon, and winter season, respectively) generated between the LST and NDWI on water bodies. On green vegetation, this LST-NDWI correlation is moderate positive (r = 0.67, 0.43, 0.50, and 0.25 in the pre-monsoon, monsoon, post-monsoon, and winter season, respectively). On human settlement and barren land surface, the correlation is weak positive (r = 0.24, 0.21, 0.27, and 0.15 in the pre-monsoon, monsoon, post-monsoon, and winter season, respectively). The output of the research work can be used in the town planning section of any urban agglomeration.