and attracted tremendous attentions, due to their wide applications in civil fields such as communication devices and aerospace vehicles. [1][2][3] On one hand, owing to the great detection technique progress achieved in the frequency region from 2 to 40 GHz with wavelength on a millimeter scale, materials with ultrabroadband microwave absorption capability covering more than four bands are highly pursued. [4][5][6][7] On the other hand, considering components and devices always work at elevated temperatures more than 1000 °C especially for aerospace vehicle applications, materials with high-temperature microwave absorption and high mechanical performance are also urgently required. [8][9][10][11] Dielectric absorption ceramics, [12][13][14] especially SiC ceramic, [15][16][17][18] are highlighted on the basis of their advantages of chemical stability, high temperature resistance, and thermal stability, which make them potential candidates for ultrabroadband and high temperature microwave absorption applications. However, the major challenge of the SiC ceramic microwave absorber like many other singlecomponent ceramic absorbents, is lack of structural designs and optimization with a low reflection profile. [4,[19][20][21] Recently, several approaches, involving uniform electrical porous lossy ceramics [22][23][24] and artificial metastructures, [25][26][27] have been proved to be effective for designing and fabricating ultrabroadband microwave absorption materials. Particularly, ceramic metastructures open a new opportunity for microwave absorption by designing the artificial periodic patterned structure configurations, and finally creating multiple absorption peaks along with additional microwave scattering based on structural influence, leading to broadband absorption. [28,29] However, these artificial ceramic metastructures are usually complex-shaped in geometries, and it is extraordinarily difficult to obtain ceramic metastructures through traditional ceramic processing and manufacturing technologies, such as powder sintering [30,31] and colloidal processing. [32,33] It is therefore highly desirable to develop an advanced and versatile technique for achieving the microwave absorbing ceramic metastructure.
Broadband microwave absorption is essential on the realms of electromagnetic compatibility and protection in civil applicationscenarios. However, coordination of material and structure is difficult without proper iterative design between material and structure resulting in insurmountable drawbacks of traditional microwave absorption medium operating under high temperature erosion. Herein, SiC metastructure is manufactured in bulk by stereolithographic 3D printing. The dielectric loss tangent of SiC sintered body is over 0.5 and up to 1.5 at most showing good electromagnetic energy dissipation properties. The optimized SiC metastructure with complicated suspended features achieves −10 dB broadband microwave absorption from 6.96 to 40 GHz at room temperature (RT) across total frequency range of 33.04 GHz. The ...