2019
DOI: 10.3390/en12203899
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Analysis and Modeling of the Wear-Out Process of a Lithium-Nickel-Manganese-Cobalt Cell during Cycling Operation under Constant Load Conditions

Abstract: This article describes the analyses of modeling the wear process of lithium-nickel-manganese-cobalt cells operating cyclically under constant load conditions. The main aging processes taking place in cells and the methodology of the modeling are discussed. The process of cell wear is examined, taking into account the influence of cyclic operating parameters (temperature, discharge current, and discharge depth). On the basis of the analyses carried out, a new function reflecting the influence of ambient tempera… Show more

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Cited by 9 publications
(6 citation statements)
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“…In the course of regular cycling at room temperature, the relatively unstable two-phase structure of LiMn 2 O 4 transforms into a stable single-phase structure with the loss of Mn3 + and the formation of MnO 2 , which transforms into inactive LiMnO 2 with a layered structure upon intercalation of lithium. When the positive electrode based on lithiummanganese spinel is overcharged to potentials below 3.5 V, the crystal structure is distorted according to Jan-Teller [91][92][93][94], which leads to dissolution of spinel and slow degradation of capacity during cycling [95].…”
Section: Processes On the Positive Electrode Of The Li-ion Batterymentioning
confidence: 99%
“…In the course of regular cycling at room temperature, the relatively unstable two-phase structure of LiMn 2 O 4 transforms into a stable single-phase structure with the loss of Mn3 + and the formation of MnO 2 , which transforms into inactive LiMnO 2 with a layered structure upon intercalation of lithium. When the positive electrode based on lithiummanganese spinel is overcharged to potentials below 3.5 V, the crystal structure is distorted according to Jan-Teller [91][92][93][94], which leads to dissolution of spinel and slow degradation of capacity during cycling [95].…”
Section: Processes On the Positive Electrode Of The Li-ion Batterymentioning
confidence: 99%
“…State of charge (SOC) is essential for Lead Acid (LA) battery to declare its well-being operation and to eliminate over-charging/deep-discharging issues. However, the complexity of the electrochemical responses marks the SOC estimation as a challenging subject [29][30][31]. In case of nonlinear systems, BPNN is the most employed technique because of its self-learning and feedback distinction [25,32].…”
Section: State Of Charge (Soc) Estimationmentioning
confidence: 99%
“…Furthermore, intensive utilization of EVs is associated with the degradation of the battery cells and acceleration of the aging processes, which are linked with the deterioration of user comfort. Analyses are often carried out using real measurement data, and models as in [49,50] are created with the purpose of determining the phenomena affecting the battery use in the V2G operations resulting from the construction and technology used. These studies most often show a deterioration in the properties of the storage facilities due to the increased frequency of the charging and discharging process under various conditions.…”
Section: Introductionmentioning
confidence: 99%