In this work, PVDF composites containing 0.2% (m/m) of carbon nanotubes (MWCNTs), PVDF with 5.0% (m/m) of zinc oxide (ZnO), and composites containing both particles in the same contents in the matrix were melt processed in a mini-extruder machine with double screws, using the counter-rotation mode. Composites were characterized by scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), X-ray diffraction (XRD), dynamic-mechanical analysis (DMA), and contact angle tests (CA). The samples presented the predominance of the α phase, with an increased degree of crystallinity as well as an increase in dimensional stability by incorporating both fillers, showing a synergistic effect between these particles, as shown on FTIR, DSC, and XRD results. SEM images showed a good dispersion of high aspect ratio particles. In general, DMA and TGA analysis showed that composites had not decreased their thermal and mechanical performance when compared to neat PVDF. Results of CA analysis showed an increase in the hydrophobicity of the sample containing MWCNTs. Permeability tests were also performed using a differential pressure system, combining high temperature and pressure, obtaining permeability measures and time lag. This work presents an alternative of composite materials, suggesting its application in the internal pressure sheath layers of oil and gas flexible pipes. K E Y W O R D S composites, nanoparticles, nanotubes, oil and gas, thermoplastics 1 | INTRODUCTION Flexible pipes are transportation lines used to connect the wells, in the seabed, to the production units, transporting oil and gas fluids in offshore applications. These pipes possess a multilayer structure, with polymeric layers and helically wound metallic wires, designed to withstand tensile loads, high pressure, and temperature. 1-3 Different layer combinations are possible, depending on the intended service conditions. Still, in general, flexible risers present a typical configuration, with the following layers: interlocked carcass (metal),