One of the most significant environmental
catastrophes throughout
the Middle East and Caucasus region has been the desiccation of Lake
Urmia, the world second-largest hypersaline lake. This lake has lost
approximately two-thirds of its water volume since 1999, resulting
in increased exposure of lacustrine deposits that are considered as
a new aerosol source. This in situ study investigates for the first
time the spatial distribution of water-soluble ion concentrations
(Cl–, Br–, NO2
–, NO3
–, SO4
2–, methanesulfonate (MSA), pyruvate, oxalate,
adipate, Na+, K+, Ca2+, Mg2+, and NH4
+) in wet deposition samples collected
around the Lake Urmia region to characterize relationships between
rainwater composition and location relative to the lake. Rainwater
collection was performed for 21 rain events from September 2017 to
September 2018 across 13 sampling stations, providing representative
coverage of the region surrounding Lake Urmia. The most dominant ions
are as follows: Ca2+ > Cl– > SO4
2– > Na+ > NO3
–. Organic acids and MSA contribute negligibly
to the total ion concentrations.
Principal component analysis (PCA) and correlation coefficient (CC)
analyses show that the majority of ions throughout the region are
associated with salt and crustal particles comprised of Cl–, Br–, SO4
2–, Na+, Ca2+, and Mg2+, with the minority
of ions (e.g., NH4
+ and NO3
–) stemming from anthropogenic emissions. Concentrations of salt and
crustal tracer species (i.e., Na+, Cl–, Br–, Mg2+, and SO4
2–) were inversely related to the distance from the
Lake Urmia shoreline, suggestive of potential subcloud scavenging
(washout) of freshly emitted aerosols. Backward trajectory analysis
(HYSPLIT) shows that most of the rain events were linked to air masses
originating in areas far upwind of Lake Urmia. Results of this study
emphasize that wet deposition data provide support for effective scavenging
of salt and crustal emissions as a function of distance from a desiccated
lakebed.