Nowadays, due to economic and climate concerns, the private transportation sector is shifting for the vehicle electrification. For this new reality, new challenges about operation modes are emerging, demanding a cooperative and dynamic operation with the power grid, guaranteeing a stable integration without omitting the power quality. Besides, new attractive and complementary technologies are offered by the vehicle electrification in the context of smart grids, valid for both on board and off board systems. In this perspective, this book chapter presents a global perspective and deals with challenges for the vehicle electrification, covering the key technologies toward a sustainable future. Among others, the flowing topics are covered: (1) Overview of battery charging systems, including on board and off board systems; (2) State of the art of communication technologies for application in the context of vehicular electrification, smart grids and smart homes; (3) Challenges and opportunities concerning wireless power transfer with bidirectional interface to the electrical grid; (4) Future perspectives about bidirectional power transfer between electric vehicles (vehicle to vehicle operation mode); (5) Unified technologies, allowing to combine functionalities of a bidirectional interface with the electrical grid and motor driver based on a single system; and (6) Smart grids and smart homes scenarios and accessible opportunities about operation modes.