Approximately 40% of the energy in traditional cars is discharged into the air through exhaust gas, causing a lot of waste of thermal energy, leading to huge economic losses. 1-3 Thermoelectric generators (TEGs) are the devices that can convert thermal energy into electrical energy, which can effectively achieve energy recovery. 4,5 Usually, the recovered electric energy is stored through a battery pack and is supplied to the vehicle-mounted electrical equipment. 6 The battery management system, as the core of battery monitoring, is widely used in electric vehicles. In software design, a reasonable algorithm is used to achieve battery state estimation and energy balance, which have a very important impact on vehicle safety. 7-12 But the system hardware structure design is also important, because the temperature of the battery pack rises during charging and discharging, the temperature between different batteries will cause the temperature in the battery pack to be inconsistent, and ultimately affect the life of the power battery. 13-15