A novel multi-stage Al production through a carbosulphidation of Al 2 O 3 , followed by a sodiothermic reduction of Al 2 S 3 , was proposed. In Stage-1, alumina (or bauxite) is reduced to Al 2 S 3 in the presence of carbon and H 2 S. In Stage-2, Al 2 S 3 is reduced to Al through reactions with Na or NaH. The thermodynamic analysis predicted Al 2 S 3 to be the main intermediate Alcompound when H 2 S is reacted with Al 2 S 3 and C at 1000-2000°C at 1 atm. Al 2 S 3 formation was predicted to be low at 1100-1300°C at 1 atm (0.1 moles/mole Al 2 O 3 ) but increased with increasing temperature (0.96 moles/mole Al 2 O 3 at 1800°C). The thermodynamic analysis of sodiothermic reduction predicted that Al metal can be extracted from Al 2 S 3 below 800°C at 1 atm. The Na 2 S produced can be hydrolysed to form H 2 S and NaOH. H 2 S can be re-used and the Na can be reproduced from NaOH and put back into the process.