This paper examines two effective surface recombination parameters: the effective surface recombination velocity S eff and the surface saturation current density J 0s. The dependence of S eff and J 0s on surface charge Q, surface dopant concentration N s , and interface parameters is derived. It is shown that for crystalline silicon at 300 K in low-injection, S eff is independent of N s only when Q 2 /N s < 1900 cm in accumulation and Q 2 /N s < 1600 cm in depletion; otherwise S eff increases with N s. These conditions are rarely satisfied in undiffused wafers but sometimes satisfied in heavily diffused wafers when coated with lowly charged films. Under the same conditions, J 0s is independent of N s when Q 2 /N s > 1.5 Â 10 7 cm for accumulation and Q 1.85 /N s > 1.5 Â 10 6 cm for inversion. These conditions are commonly satisfied in undiffused wafers but rarely in diffused wafers. We conclude that for undiffused silicon, J 0s is superior to the conventional S eff as a metric for quantifying the surface passivation, whereas for diffused silicon, the merit in using J 0s or S eff (or neither) depends on the sample. Experimental examples are given that illustrate the merits and flaws of J 0s and S eff .